hydrocarbons (benzene compounds)ketones (benzene compounds)Die Friedel-Crafts-Alkylierung des Benzols (I) gelingt auch mit den Acylchloriden (II).doi:10.1002/chin.197517219ERIK DAHLBERGPER MARTINSONKARE OLSSONJohn Wiley & Sons, LtdChemischer Informationsdienst...
Friedel Craft’s acylation reaction:When benzene is treated with an acyl halide in the presence of Lewis acid such as anhydrous aluminum chloride, acyl benzene is formed. This reaction is popularly known as Friedel Craft’s acylation reaction. ...
VII. Friedel-Crafts Reactions of 1,3,5-Trineopentylbenzene with Acyl Chlorides and Preparations of Some Chloro Derivatives of 1,... Die Friedel-Crafts-Alkylierung des Benzols (I) gelingt auch mit den Acylchloriden (II). Dahlberg,Erik,Martinson,... - 《Acta Chemica Scandinavica》 被引量:...
KeywordsTask-specificionicliquids,[Bis(trifluoroacetoxy)iodo]benzene,1-Methylimidazole,Acylamide, Acetoxylation 双(三氟乙酰氧基)碘苯([bis(trifluoroacetoxy)iodo]benzene,BTI)试剂在有机合成中具有广泛的应用。 由于氟原子的强吸电子作用,BTI试剂通常比它的类似物二乙酰氧基碘苯[(diacetoxyiodo)benzene,DIB] 具有...
3-Trimethylbenzene with an acylating agent to introduce an acyl functional group onto the benzene ring. For example, reacting 1,2,3-Trimethylbenzene with acetic anhydride yields 1,2,3-Trimethylbenzene acetate. Alkylation reaction replaces the methyl group on the benzene ring with an alkyl group...
A process for the preparation of acyl benzene Involving the reaction of di-acetoxybenzoyl chloride with a Grignard reagent in the presence of a catalyst containing iron, a process for the preparation of the acyl benzene is provided. Acyl benzene are very useful intermediates for the... ジェフ...
Among obtained derivatives compound 31 (IC50 = 43.84 ± 0.29 µg/mL) showed higher activity than other benzenesulfonyl hydrazones but lower than 5-fluorouracyl (IC50 = 0.21 ± 0.00 µg/mL) (Fig. 20). The same compound showed higher activity towards C6 cell line, ...
Then one of the c-o bonds on the Oxygen will break heterolytically and go to the oxygen leaving you with an acyl group and AlCl3--Junk. The acyl group will then attack the benzene as usual. Hope this is helpful. Logged vietknight ...
The results of the interaction of cetyltrimethylammonium bromide (CTAB) and sodium dodecyl sulfate (SDS) with sodium cholate (NaC), sodium deoxycholate (Na... PK Jana,SP Moulik - 《J.phys.chem》 被引量: 222发表: 1991年 Thermodynamics of micellization of benzyl(2-acylaminoethyl)dimethylammonium...
of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride...