Fluoride Ion Sensing by an Anion-π Interaction. J. Am. Chem. Soc. 2010, 132, 17674-17677.Fluoride Ion Sensing by an Anion?π Interaction. Samit Guha,Sourav Saha. Journal of the American Chemical Society . 2010Fluoride ion sensing by an anion-π interaction. Guha, Samit,Saha, Sourav. ...
We have studied the additivity of the anion-pi interaction using high level ab initio calculations. We have optimized chloride and bromide complexes with one, two and three aromatic units (such as trifluoro-s-triazine and s-triazine). We have analyzed the interaction using the atoms in molecule...
The predominant interaction motif is C-H center dot center dot center dot anion hydrogen bonding. 机译:在剑桥结构数据库中,有关平面六元环上阴离子分布的深入分析表明,阴离子-pi与电荷中性pi系统的相互作用在晶体结构中极为罕见。主要的相互作用基序是C-H中心点中心点中心点阴离子氢键。 著录项 来源 ...
Putting the Anionπ Interaction in Perspective Anionπ interactions are increasingly reported in the recent literature. Although many of these examples are described to be unique, a careful look in the ... TJ Mooibroek,CA Black,P Gamez,... - 《Crystal Growth & Design》 被引量: 208发表: ...
Cation-pi and anion-pi interactionsIn this review, we analyze the interaction of ions with aromatic ringsFronteraQuioneroDeyàCation-pi and anion-pi interactions. Antonio Frontera,David Quinonero,Pere M. Deya. WILEY INTERDISCIPLINARY REVIEWS-COMPUTATIONAL MOLECULAR SCIENCE . 2011...
The importance of anion-pi interactions has been widely demonstrated by a great deal of theoretical and experimental investigations. These interaction are gaining significant recognition, and their pivotal role in many key chemical and biological processes is becoming increasingly appreciated. The design of...
Venturoli G, Fernàndez-Velasco JG, Crofts AR, Melandri BA (1986) Demonstration of a collisional interaction of ubiquinol with the ubiquinol–cytochrome c2 oxidoreductase complex in chromatophores from Rhodobacter sphaeroides. Biochim Biophys Acta 851:340–352 Article CAS Google Scholar Yang G, Zou H...
The anion-pi interaction energies are distance and orientation dependent. It was found that anion-pi interactions showed energy less than -15 kcal mol(-1), and most of them have energy in the range -2 to -9 kcal mol(-1). Solvent accessibility pattern of Sm/LSm proteins reveals that all...
The importance of anion-pi interactions has been widely demonstrated by a great deal of theoretical and experimental investigations. These interaction are gaining significant recognition, and their pivotal role in many key chemical and biological processes is becoming increasingly appreciated. The design ...
anion-pi interaction with interactions involving halide anions being dominated by electrostatic and the induction energies.On the other hand,dispersion energies are markedly higher in interactions involving organic anions.Apart from aiding an understanding of the origin of anion-pi interaction,we believe ...