The importance of anion-pi interactions has been widely demonstrated by a great deal of theoretical and experimental investigations. These interaction are gaining significant recognition, and their pivotal role in many key chemical and biological processes is becoming increasingly appreciated. The design ...
This tutorial review provides an overview of the theoretical and experimental investigations that resulted in the recognition of anion-pi interactions, i.e., non-covalent forces between electron deficient aromatic systems and anions. Several pioneering theoretical studies revealed that these interactions are...
a0,3 mm - mask for the glue. 0,3毫米-面具为胶浆。[translate] aentrr you entrr您[translate] aThermodynamics of Anion-pi Interactions in Aqueous Solution 阴离子pi互作用热力学在水溶液[translate]
We also report crystallographic evidence derived from the solid-state structure of the dinuclear metallocycle in support of the existence of anion-pi-pi interactions.关键词: Anodes Cathodes Density measurement Electric variables measurement Electron beams Magnetic field measurement Magnetic fields Numerical ...
Combined Cation-pi and Anion-pi Interactions for Zwitterion RecognitionPerraud, ORobert, VGornitzka, HMartinez, ADutasta, J PPerraud O, Robert V, Gornitzka H, Martinez A, Dutasta J-P (2012) Combined cation–π and anion–π interactions for zwitterion recognition. Angew Chem Int Ed 51:...
1. Anion-pi Interactions in Crystal Structures: Commonplace or Extraordinary? [J] . Hay BP, Custelcean R Crystal growth & design . 2009,第6期 机译:晶体结构中的阴离子-π相互作用:是平常的还是非凡的? 2. Molybdenum(VI) network polymers based on anion-pi interaction and hydrogen bonding: Sy...
Salt-bridge-[small pi] (sb-[small pi]) Interactions at Work: Associative Interactions of sb-[small pi], [small pi]-[small pi] and Anion-[small pi] in Cu(II... Salt-bridge-[small pi] (sb-[small pi]) Interactions at Work: Associative Interactions of sb-[small pi], [small pi]-...
In this study, the importance of anion-pi interactions in four-membered rings has been evidenced. Two kinds of rings have been found to be suitable for participation in anion-pi interactions: first, in different salts of cyclobuten-1,2-dione derivatives and, second, in eta(4)-cyclobutadiene...
Computational studies highlight the importance of the arene quadrupole moment, molecular polarizability, and substituent effects on the strength of anion-pi interactions. More importantly, however, this work establishes that there is a distinct directionality inherent to the anion-pi interaction between ...
center dot center dot center dot pi and anion center dot center dot center dot pi interactions are examined and related. 机译:单核镍(II)和铜(II)配合物,即(C6H9N2)(2)[Ni(ntaH)(2)](1),(C5H7N2)(2)[Cu(mal)(2)(H2O) (2)](2)和(C5H7N2)(4)[Ni(mal)(2)(H2O)(2)](NO3)...