Catalysis with Anion-π Interactions. Angew. Chem., Int. Ed. 2013, 52, 9940-9943.Zhao, Y.; Domoto, Y.; Orentas, E.; Beuchat, C.; Emery, D.; Mareda, J.; Sakai, N.; Matile, S. Catalysis with anion-π interactions. Angew. Chem., Int. Ed. 2013, 52, 9940-9943....
摘要: The conclusion is inevitable: Increasing stabilization of an anionic transition state with increasing π-acidity of the catalyst is observed; thus, anion-π interactions can contribute to catalysis.关键词: Molekulare Erkennung Nichtkovalente Wechselwirkungen Organokatalyse Reaktionskinetik Über...
Putting Anion‐π Interactions at Work for Catalysis Since its discovery two decades ago, anion‐π interaction has been increasingly recognized as an important driving force. Extensive theoretical and experi... N Luo,Y Ao,WQ Wang - 《Chemistry A European Journal》 被引量: 0发表: 2022年 Poly...
The development of anode catalysts for anion-exchange membrane fuel cells is promising but challenging in practical applications. Here, the authors report the tiny single-atom alloy nanoparticles that catalyze hydrogen oxidation reaction with very high activity, stability, and CO resistance. ...
Fast and selective reduction of nitroarenes under visible light with an earth-abundant plasmonic photocatalyst A low-cost plasmonic photocatalyst based on earth-abundant metals (Fe, Cu) maximizes solar energy conversion due to the concerted interplay of energies and interactions between reactants and ...
we argue that the strength of the electric field at the catalyst surface is sensitive to the molecular identity of the organic cation in the electrolyte. This is true irrespective of solvent, electrolyte ionic strength or electrolyte anion. Our results suggest that changes in the interfacial electri...
A crucial task towards creating a sustainable chemical industry is the electrification of chemical processes that produce value-added molecules. One such molecule is 1,3-butadiene (1,3-BD), the feedstock used for manufacturing synthetic rubber. 1,3-BD is
56.Modeling of the Interactions Between Catalytic Surfaces and Gas-Phase 机译:催化表面与气相之间相互作用的建模 作者:Deutschmann Olaf 期刊名称:《Catalysis Letters》 | 2015年第1期 关键词: Heterogeneous catalysis; Gas-phase kinetics; Surface reaction kinetics; Auto-thermal reforming; Combustion; Part...
Compared with results obtained under neutral conditions, experimental and calculation results for the cobalt sites in alkaline electrolytes demonstrated lower activation energies, different pH-dependent redox features, lower KIEs, negligible reaction order with respect to the external anion and absence of ...
4c, d), which together with the interactions of Pi with Tyr394 and Lys398 (Supplementary Fig. 4a), may be necessary for the glutaminase enzymes to undergo the dimer-to-tetramer transition, a prerequisite for filament formation and catalytic activity. Interestingly, in the filament structure for...