Diverse and wide range of applications of the thiol-ene "click chemistry" has been demonstrated, including the preparation of biocompatible materials and materials for culture and encapsulation of cells; the synthesis of block copolymers; the development of degradable materials as well...
In this work, the thiol-ene click reaction is employed to fabricate polymer-dispersed liquid crystal (PDLC) films by photoinitiated polymerization. The PDLC films are prepared by systematic variation of key conditions: variety and content of -ene monomer, liquid crystal (LC) content, curing time,...
Novel bifunctional antioxidants (AO) with high molecular weight were successfully synthesized by two-step free-radical thiol-ene click reaction and transesterification. The structures of the stabilizers were confirmed by 1H NMR spectra and Fourier Transform Infrared Spectrometry (FTIR). Thermal gravimetric...
The resulting compound was used as a flexible, conductive crosslinker to form a soft injectable hydrogel with thiol-modified hyaluronic acid through a “thiol-ene” click reaction. In order to enhance the stability and conductivity of the matrix, GO nanosheets were incorporated into the hydrogel. ...
YOU YeZi CAS Key Lab of Soft Matter Chemistry;Department of Polymer Science and Engineering,University of Science and Technology of China,Hefei 230026,China.One-pot synthesis of hyperbranched poly(amido amine) clicked with a sugar shell via Michael addition polymerization and thiol click reaction[J]...
Thiol‐ene click chemistry was employed to form microspheres with sugar groups with high bioactivity and efficient binding of Concanavalin A. Two systems were investigated – a microsphere prepared from ethyleneglycol dimethacrylate, which contained excess vinyl functionalities as a natural result of the ...
L., Thiol-ene click reaction as a general route to functional trialkoxysilanes for surface coating applications. Journal of the American Chemical Society 2011, 133 (29), 11026-9.Recent applications of thiol-ene coupling as a click process for glycoconjugation. Alessandro Dondoni,Alberto Marra. ...
Subsequent thiol–ene or thiol–yne reaction with thioglycolic acid or 2-mercaptosuccinic acid leads to polymers with carboxylate functionalities, which were conjugated with cisplatin (cis-diamminedichloroplatinum(II) (CDDP)) to generate a drug carrier for Pt-drugs. Only the polymers modified with 2...
Thiol-ene click reactions led to fluorescent cholesterol- and folic acid-functionalized polyvinylphosphonates. Turbidity measurements in complex biological fluids could show the retention of the thermoresponsive properties. Concluding the confocal microscopy experiments proved to selective cellular uptake of the...
thiol–ene click chemistryFunctionalized pyrrolidinium compounds, 3-((2-hydroxyethylthio)methyl)-1,1,4-trimethylpyrrolidinium and 3-((2-carboxyethylthio)methyl)-1,1,4-trimethylpyrrolidinium chlorides, are prepared from N,N-diallyl-N,N-dimethylammonium chloride by radical thiol-ene addition and are ...