2-Methylimidazole palladium(II) complexesThe preparation of two new tetracoordinated complexes of palladium(II) with 2-methylimidazole, 2-MeIm, and chloride as ligands is described.doi:10.1007/BF00619475M José CamazónAmparo Alvarez-ValdésJosé R. MasaguerM. Carmen Navarro-Ranninger...
The syntheses, FT-IR and UV–Vis spectra, thermal analyses and crystal structures of Mn(II) and Cu(II) orotate coordination polymers with 2-methylimidazole (2-meim) and N,N,N′ ,N′-tetramethylethylenediamine (tmen) ligands are described. The orotate ligand acts as a bridging ligand with...
The synthesis and detailed study of the new mononuclear spin crossover complex [Fe(II)H2L(2-Me)](ClO4)2 (where H2L(2-Me) = bis[((2-methylimidazol-4-yl)meth... N Bréfuel,S Imatomi,H Torigoe,... - 《Inorganic Chemistry》 被引量: 55发表: 2006年 A study of the thermal and ...
The 4-MeIm ligands are N-coordinated in cis positions. The complex crystallizes in the triclinic space group p1 with unit cell parameters a = 9.204(5), b = 9.498(5), c = 13.095(5) , α = 90.395(5), β = 101.687(5), γ = 112.291(5)° and Z = 2. Hydrogen bondings and C-...
2-Methylimidazole (2-MeIm) reacts with RuCl[sub 3] in aqueous acidic ethanolic medium to give (2-MeImH)[sub 2] [RuCl[sub 5] (2-MeIm)] (1) and (2-MeImH)[RuCl[sub 4] (2-MeIm)[sub 2] ] (2) (2-MeImH = protonated 2-methylimidazole), the ratio depending on reaction ...
Copper(II), ruthenium(III) and zinc(II) complexes of 2-methylimidazole (2-MeImzlH) encapsulated in the supercages of zeolite-Y have been synthesized and characterized by various physicochemical measurements. The catalytic potential of these complexes were tested for the oxidation of phenol and ...
Spectral changes in the increased amount of 2-MeImH; Resonance Raman spactral changes; Photoreduction of iron porphyrin.UnoTadayukiHatanoKeiichiroJournal of the American Chemical Society
[(CH3)(2)NH2][Co-3(BTC)(HCOO)(4)(H2O)]H2O (Co-BTC) was synthesized under solvothermal conditions, further used as the precursor for the synthesis of 2-methylimidazole modified Co-BTC (2MeIm@Co-BTC-x). The characteristics of 2MeIm@Co-BTC-x were systematically characterized by various...
Two new mixed-ligand coordination polymers, {[Co(μ1,3-sq)(H2O)2(2-Meim)2]·2(2-Meim)}n (1) and [Cd(μ1,3-sq)(H2O)2(4(5)-Meim)2]n (2), (sq = squarate, 2-Meim = 2-methylimidazole, 4(5)-Meim = 5-methylimidazole) have been synthesized and structurally...
Novel zinc(II) coordination polymer [Zn(Pht)(Im)(2)](n) (1), unique cyclic dimer [Zn(Pht)(Im)(H2O)](2) (2) and coordination polymer [Zn(Pht)(2-MeIm)](n) (3) (where Pht(2-) = dianion of o-phthalic acid, Im = imidazole, 2-MeIm = 2-methylimidazole) have been ...