PPh 2Py preserves the dinuclear structure of Ru(I) complexes [Ru 2(渭-RCOO) 2(CO) 4(PPh 2Py) 2] (R = H ( 1) and Me ( 2)).On the other hand, the reaction with PPh 2CH 2Py leads to the formation of mononuclear ionic Ru(II) complexes of the type [Ru(RCOO)(PPh 2CH 2...
The cluster compounds, [MoAu2S4(PPh2Py)2] (1) and [WAu2S4(PPh2Py)2] (2), were synthesized by the reaction of (NH4)2MS4 (M = Mo, W), H[AuCl4]·4H2O and diphenyl-2-pyridyl-phosphine (PPh2Py) in CH2Cl2 solution. [MoAu2S4(PPh2Py)2] crystallizes in the monoclinic space ...
Under mild conditions, the reaction of Co2(CO)8 with HC CSiMe3 in the presence of PPh2py gave a binuclear cobalt carbonyl complex, Co2(CO)4(η2-μ2-HC CSiMe3)(μ-PPh2py) (1a), which has both zero-valent cobalt centers coordinated by a bidentate ligand, PPh2py. PPh2py is also ...
The reaction of the Tc(II) nitrosyl complex (Bu4N)[Tc(NO)Cl-4] with excess pyPPh(2) in refluxing MeOH gives the bis-pyridyl-diphenylphosphine complex [TcCl... T Nicholson,M Hirschkuchma,A Shellenbargerjones,... - 《Inorganica Chimica Acta》 被引量: 28发表: 1998年 The synthesis and...
The three-coordinate tris(2-pyridylphosphine)palladium(0) complex is the first example of a group 10 metal complex bearing pyridine substituted phosphine ligand, whose crystal structure is determined. Pd(PPh2py)3 crystallizes in the triclinic space group , with a = 12.874(4) , b = 14.162(3...
Email:info@coreychem.com Products Intro:Product Name:Ru(ifpz)2(PPh2Me)2 , Bis(3-trifluoromethyl-5-(1-isoquinolyl)py CAS:934276-37-6 Purity:98% Package:25kg;100kgMore... CB Index:58 WebSite:www.coreychem.com Related Information:Sales NetworkCatalog(10453)User Evaluation...
The complexes [RuCl(PPh(3))(2)(P,N,N'-PPh(3-)(x)()(py)(x)())]PF(6) (x = 2, 1b; 3, 1c; py = 2-pyridyl) were isolated from the reaction of RuCl(2)(PPh(3))(3)... GJ Kubas,GD Jarvinen,RR Ryan - 《Journal of the American Chemical Society》 被引量: 41发表: 19...
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Luminescent polymorphic aggregates of trinuclear Cu(I)-pyrazolate tuned by intertrimeric CuNPy weak coordination bonds. Dalton Trans. 2021, 50, 1733–1739. [Google Scholar] [CrossRef] Chen, X.-L.; Yu, R.; Zhang, Q.-K.; Zhou, L.-J.; Wu, X.-Y.; Zhang, Q.; Lu, C.-Z. ...
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