Is RuH 4 (PPh 3 ) 3 in solution indeed a non-classical hydride?doi:10.1016/S0020-1693(00)85878-8A novel systematic investigation of temperature dependences of 1H, 2H, 31P NMR spectra and 1H T1, T2 and 2H T1 relaxation times has been carried out for solutions of RuH4(PPh3)3 (5) ...
X-ray Crystal Structure of (PPh(3))HRu(&mgr;-H)(&mgr;-PMe(2)C(5)Me(4))(2)(&mgr;-Cl)ZrCl. The new isomeric ruthenium/zirconium dihydrides of the formula (PPh(3))HRuH(&mgr;-PMe(2)Cp)(2)ClZrCl (1, 2) (Cp = C(5)Me(4)) have been characterized by elemental analysis ...
pdcl2(pph3)2和pd(pph3)4的分化方法[指南] 文档格式: .doc 文档大小: 19.0K 文档页数: 1页 顶/踩数: 0/0 收藏人数: 0 评论次数: 0 文档热度: 文档分类: 待分类 文档标签: pdcl240pph3412和pd40pph3414的分化方法指南 系统标签: 甲醇加入氯化氮气保护苯基pdcl分化 ...
Cheng, Xin,Ma, Shengming.[Pd(PPh 3 ) 4 ]-catalyzed diastereoselective synthesis of trans-1,2-diazetidines from 2,3-allenyl hydrazines and aryl halides.Angewandte Chemie - International Edition. 2008Cheng X,Ma S M.[Pd(PPh3)4]-Catalyzed Diastereoselective Synthesis of trans-1,2-Diazetidine...
RuH2(PPh3)4: An Active Catalyst for Living Radical Polymerization of Methyl Methacrylate at or above Room Temperature1 RuH2(PPh3)4:An Active Catalyst for Living Radical Polymerization of Methyl Methacrylate at or above Room Temperature1[J].Macromolecules,1999,(20):6461-6465.doi:10.1021/ma990...
In this study we have restricted our attention to Fe(CO)4PPh3. The coordination of a large phosphine, PPh3, renders the vapor pressure of the complex sufficiently low that evaporation of the starting material during the study is inconsequential. It should be noted that the PPh3 ligand will ha...
N-Fluorobenzenesulfonimidel-ProlineThe halogenation of 2-furan benzothiazole fails.doi:10.1002/chin.201427145Ding, QiupingYe, ChangqingPu, ShouzhiCao, BanpengJohn Wiley & Sons, Ltd.ChemInformPd(PPh 3 ) 4 -catalyzed direct ortho -fluorination of 2-arylbenzothiazoles with an electrophilic fluoride N...
The [Sn(9)Pt(2)(PPh(3))](2)(-) and [Sn(9)Ni(2)(CO)](3)(-) complexes: two markedly different Sn(9)M(2)L transition metal zintl ion clusters and their dynamic behavior Kesanki B., Fettinger J., Gardner D.R., Eichhorn B., The [Sn9Pt2(PPh3)]2- and [Sn9Ni2(CO)]3-...
The PPh-substituted hydroxycyclopentadienyl ruthenium hydride [2,5-Ph-3,4-Tol(η-CCOH)]Ru(CO)(PPh)H () stoichiometrically reduces aldehydes and ketones in the presence of a pyridine trap to produce alcohols and the ruthenium pyridine complex , with a rate law that is dependent only on [ald...