cAMP-regulated phosphoprotein-19HA-detection, intrinsically disordered proteinNMR spectroscopyProtein Phosphatase 2A, PP2A, the principal Serine/threonine phosphatase, has major roles in broad range of signaling pathways that include regulation of cell cycle, cell proliferation and neuronal signaling. The ...
将”N-NMR化学位移影响规律与相应的1H-N躲、13C-NMR、170-NMR作不同程度 的比较,简单分析了它们之间的关系。 关键词:含氮化合物;15N-NMR;化学位移;取代基效应 THESTUDYOF15N.NMRCHEMICALSHIFTS RULES ABSTRACT Basedonthe systematical summarizationand analysis of reported dataof”N.NMRchemicalshift.thelinear ...
Biomolecular NMR Assignments (2023) 17:257–263 https://doi.org/10.1007/s12104-023-10151-5 ARTICLE 1H, 13C, and 15N NMR chemical shift assignment of LytM N‑terminal domain (residues 26–184) Ilona Pitkänen1 · Helena Tossavainen1 · Perttu Permi1,2,3 ...
NMR 化学位移误差为 Δδ±5 ,是可以允许的 . 公式( 1 )中约有 94.7% 的 15 NNMR 化学 位移计算值的计算误差在 δ5.0 的范围内(相对误差小于 0.5% ),这说明公式( 1 )基本能 够准确地计算脂肪胺类化合物氨基氮 15 NNMR 的化学位移 . 表 2 计算脂肪胺氨基氮 15 犖犖犕犚 化学位移时采用的取代基...
若数据不同则主要依据较新文献提供的校正过的数据或在较稀 的惰性溶剂中测定的数据. 表1 计算苯甲醛亚胺 犘犺犆犎=犖 犡亚胺基氮15犖犖犕犚化学位移时采用的取代基参数 15 Table1TheSubstituentChemicalShiftsforcalculatinNNMRchemicalshift g ofhenliminesPhCH=NX py SubstituentChemicalShiftsofX SubstituentX () ...
Secondary chemical shift analysis is the main NMR method for detection of transiently formed secondary structure in intrinsically disordered proteins. The ... M Kjaergaard,S Brander,FM Poulsen - 《Journal of Biomolecular Nmr》 被引量: 178发表: 2011年 Random-coil chemical shifts of phosphorylated am...
{1H} NMR spectrum of1*in D8-THF (Fig.2a) exhibits a single isotropic chemical shift (δiso) resonance at 968.9 ppm relative to the IUPAC standard of MeNO2at 0 ppm45. The analogous spectrum of1*in D6-benzene exhibits a resonance atδiso972.6 ppm, demonstrating little polar/...
Pyridine and aminide derivatives as ligands in 1 : 1 Rh2[tfa]4 adducts: 1H, 13C and 15N NMR study 来自 EBSCO 喜欢 0 阅读量: 37 作者:Jaros?aw Ja?wiński,Helmut Duddeck 摘要: 1H, 13C and 15N chemical shifts of some pyridines and mesoionic oxatriazole aminides were recorded in the ...
1H, 15N and 13C chemical shift assignments for the winged helix domains of two archeal MCM C-termini . Biomol. NMR Assign. Epub ahead of print (2013).Wiedemann C, Ohlenschläger O, Medagli B, Onesti S, Görlach M (2013) (1)H, (15)N and (13)C chemical shift assignments for ...
A similar sensitivity enhancement was also obtained for 2D 15N–1H dipolar and 15N chemical shift correlation spectroscopy, by means of a 3D 1H/15N–1H/15N correlation experiment. We demonstrate this technique, termed PRINS for proton indirectly detected nitrogen static NMR, on a crystalline model ...