alpha-AMINONITRILES DERIVED FROM FATTY ALKYL ALKYLENE DIAMINESalpha-aminonitrile compounds derived from a fatty alkyl alkylene diamine containing two reactible amino functionalities are disclosed.FLEMING ALISON A[US]FARMER ROBERT F[US]GADBERRY JAMES F[US]...
A method for producing an α-aminonitrile, is disclosed, which method includes the step of oxidizing a tertiary amine with oxygen by using a transition metal catalyst in the presence of a cyanide. The α-aminonitrile thus obtained can be easily converted to amino acids as well as various ...
n - hydroxylated alpha aminosaeure, amide, and other derivatives. with an aromatic aldehyde to form a Schiff base, oxidizing the Schiff base to an oxaziridine and converting the oxaziridine into the corresponding N-... J Kamphuis,WHJ Boesten 被引量: 0发表: 1993年 加载更多研究...
PROBLEM TO BE SOLVED: To provide a new method for producing an optically active α- aminonitrile and optically active α-amino acids are obtained from the aminonitrile. The α-aminonitrile is obtained by asymmetric synthesis in high yield and with high stereoselectivity without syn...
PROBLEM TO BE SOLVED: To provide a method for producing an α-aminonitrile by which reaction steps are simplified in after-treatment of reaction and the operation for purification or isolation, and the α-aminonitrile is utilized in automatic synthesis or combinatorial chemistry.SUGINOME MICHINORI...
PROBLEM TO BE SOLVED: To provide a method for producing an α-aminonitrile by which reaction steps are simplified in after-treatment of reaction and the operation for purification or isolation, and the α-aminonitrile is utilized in automatic synthesis or combinatorial chemistry.;SOLUTION: A bis(...
PROBLEM TO BE SOLVED: To extremely cleanly and efficiently carry out a reaction for obtaining an α-aminonitrile from a tertiary amine by using readily available and inexpensive sodium cyanide and molecular oxygen without producing by-products.MURAHASHI SHUNICHI...
it relates in particular to a process for synthesis of alpha aminonitriles is to subject to the action of the metal, a reducing agent to form an imine metal wire and then treating it by a mining agent to produce a compound of formula (i).the compounds of formula (i) are useful ...
The synthesis of new indole alkaloid analogues, containing a 1,2,4,5,10b,10c-hexahydropyrrolo[1',2',3':1,9a,9]imidazo[1,2-a]indole skeleton, via highly stereoselective novel domino cyclative halogenation or prenylation reactions of tryptophan-derived alpha-amino nitriles, is described.关键词...
An alpha-aminonitrile compound can be formed by reaction of an amino sugar, such as glucamine or glucosamine, a carbonyl compound, such as a bisulfite adduct of an aldehyde, and a cyanide source, such as an alkali metal cyanide.Fleming, Alison A....