The main focus of this review is on the detail study of stability as well as the factors affecting the stability of Zr-based MOFs, including the adsorbent capacities, thermodynamics and kinetic studies. Moreover we have discussed the introduction of metal ions to organic linkers having more ...
This approach is also applicable to other Zr-based MOFs to enhance CO2 photocatalytic reduction under UV–visible light. In-situ Fourier transform infrared and density functional theory calculations reveal the reaction intermediates and lower energy barrier for the rate-limiting step of *CO formation ...
The structural stability of MOFs against water plays a dominant role in their adsorption performance. UiO-66, as exceptional water and pH stable MOF, has drawn attention for the heavy metal ions removal from industrial effluents. UiO-66 is the most attractive Zr-based framework built up from ca...
Among the large family of metal–organic frameworks (MOFs), Zr-based MOFs, which exhibit rich structure types, outstanding stability, intriguing properties and functions, are foreseen as one of the most promising MOF materials for practical applications. Although this specific type of MOF is still ...
Ce(111) Doped Zr-Based MOFs as Excellent NO2 Adsorbents at Ambient Conditions New hybrid cerium modified zirconium based metal—o AM Ebrahim,TJ Bandosz - 《Acs Applied Materials & Interfaces》 被引量: 17发表: 2013年 Ce(111) Doped Zr-Based MOFs as Excellent NO2 Adsorbents at Ambient ...
38. The UiO-66 catalysts synthesized in ILs are much more active than that produced by solvothermal method (Supplementary Figs.18–21). The high catalytic activities of the UiO-66 catalysts synthesized in this work can be ascribed to their unique features. First, in comparison with the MOFs ...
(H2bzpdc)isusedheretoselectivelyfunctionalizetheMOFsurface.Wereportthedirectradical-inducedoxidativegrafting-frompolymerizationoftheprecursorEDOTonZr-bzpdc-MOF,leadingtoanelectricallyconductivecompositematerialandopeningtheroadtoavarietyofapplications.Metal–organicframeworks(MOFs)featureanorderedstructurewithpermanentporosity...
Consequently, it is essential to control the adsorption of water and the stability of the MOF in the presence of water in liquid and/or gaseous states.9,11,12 In particular, it has been shown that Zr-based MOFs, such as UiO-66(Zr), benefit from a high stability in the presence of ...
Amani M E,Teresa J B.Ce(III)-doped Zr-based MOFs as excellent NO2adsorbents at ambient conditions[J].ACS Appl Mater Interfaces,2013,5(21):10565-... AM Ebrahim,TJ Bandosz - 《Acs Applied Materials & Interfaces》 被引量: 17发表: 2013年 Availability of Zr-Based MOFs for the degradation...
MOFs water adsorption Introduction In the past 20 years, research in the area of metal–organic frameworks (MOFs) has delivered various record-holding materials in terms of surface area [1] and gas storage [2] and has also given rise to unprecedented adsorption phenomena [3] often associated ...