In comparison with microporous UiO-66, a model protein of cytochrome c (Cyt c) could be efficiently loaded into the mesoporous MOFs (mesoMOFs). The size-dependent cellular uptake is also evaluated, and it is verified that mesoMOFs with particle size of 90 nm could be endocytosed into ...
Among the large family of metal–organic frameworks (MOFs), Zr-based MOFs, which exhibit rich structure types, outstanding stability, intriguing properties and functions, are foreseen as one of the most promising MOF materials for practical applications. Although this specific type of MOF is still ...
Ce(111) Doped Zr-Based MOFs as Excellent NO2 Adsorbents at Ambient Conditions New hybrid cerium modified zirconium based metal—o Amani,M.,Ebrahim,... - 《Acs Applied Materials & Interfaces》 被引量: 17发表: 2013年 Ce(111) Doped Zr-Based MOFs as Excellent NO2 Adsorbents at Ambient ...
Surface modification, defect engineering and doping modification of materials have been investigated to enhance the gas-binding capacity of MOFs. Given that the properties of transpiration water, produced by fruit metabolism, bear a resemblance to those of gas, these strategies can serve as valuable ...
Herein, the CO2 adsorption in MIP-202-P1 purely relies on physical adsorption, and the value is comparable to the reported MIP MOFs and lower than many previous studied adsorbents (Table S3). The low Qst indicates less energy is required for adsorbent regeneration, making MIP-202 particles as...
Metal–organic frameworks (MOFs) have been the subject of extensive scientific investigation in the last three decades and, currently, they make up one of the types of compounds most studied for their potential application in a wide range of distinct catalytic processes. Pristine MOF compounds provi...
With this goal in mind, a dual ultraviolet visible and electron paramagnetic spectroscopy approach has been applied to determine the Cr speciation within Zr‐based metal﹐rganic frameworks (MOFs). Our findings point out that the generation of defect positions at Zr㎝OFs boost Cr VI adsorption, ...
In the current work, facilely synthesized Zr-based metal–organic frameworks (MOFs) of UiO-66 and UiO-67 have been successfully exploited as novel affinity materials for the enrichment and analysis of phosphopeptides. Thanks to their abundantly existent and naturally exposed Zr–O clusters, ...
Rational design and facile synthesis of thiol-modified metal–organic frameworks (MOFs) for the efficient capture of highly toxic mercuric ions from water has attracted great attention. However, the corresponding adsorption mechanism is not well understood. In this paper, a thiol-modified Zr-based MO...
38. The UiO-66 catalysts synthesized in ILs are much more active than that produced by solvothermal method (Supplementary Figs.18–21). The high catalytic activities of the UiO-66 catalysts synthesized in this work can be ascribed to their unique features. First, in comparison with the MOFs ...