论文2:Formation of CuMn Prussian Blue Analog Double-Shelled Nanoboxes Toward Long-Life Zn-ion Batteries 图3 Mn2p分峰拟合结果 这篇论文发表在了Angewan上,而且作者中也有不少大牛,说明整体工作是非常好的,我们这里只对XPS部分进行简单的分析。本文中,作者制备了一种CuMn普鲁士蓝类似物,为了表征材料中Mn的...
Dong G S,Xu M,Chen Y,et al.XPS study of Mn thin films grown on GaAs(001) surface. Surface and Interface Analysis . 1996Dong G S , Xu M , Chen Y , et al . XPS study of Mn t hin films grown on GaAs (001) surface[J ] . S urf ace and Interf ace analysis , 1996 , 2...
此外，非活性 Mn4+的存在导致阳离子氧化还原的减少，这可能导致氧化还原反应中氧的高参与。参考文献 Li, Y., Hu, Y., Zhao, Y., & Zhang, J. (2020). In situ and operando X-ray photoelectron spectroscopy studies of electrode materials for rechargeable batteries. Chemical Society Reviews, 49(11),...
当放电到 1.5 V 时,该峰消失,证明了氧氧化还原反应具有良好的可逆活性。此外,非活性 Mn4+的存在导致阳离子氧化还原的减少,这可能导致氧化还原反应中氧的高参与。 参考文献 Li, Y., Hu, Y., Zhao, Y., & Zhang, J. (2020). In situ and operando X-ray photoelectron spectroscopy studies of electrode...
不是每个元素都产生多重分裂峰,通常稀土金属(4f轨道上有未成对电子存在)的4s能级表现有强的分裂,过渡金属(3d轨道上有未成对电子存在)的3s能级表现有强的分裂,例如Mn 3s。因此利用s能级的多重分裂现象可以研究分子中未成对电子的存在情况,同时帮助化学态鉴别。
Presents a study which focused on the 2p3/2 X-ray photoelectron spectra (XPS) of Mn2+, Mn3+, and Mn4+ ions of some Mn-bearing oxides and oxyhydroxides, including manganite and synthetic birnessite. Information on experimental procedures used; What controls the formation rate of birnessite; ...
XPS表征手册一般采用:Chastain, Jill, andRoger C. King, eds. Handbook of X-ray photoelectron spectroscopy: a reference book of standard spectra for identification and interpretation of XPS data. Eden Prairie, MN: Physical Electronics, 1995.
XPS表征手册一般采用:Chastain, Jill, andRoger C. King, eds. Handbook of X-ray photoelectron spectroscopy: a reference book of standard spectra for identification and interpretation of XPS data. Eden Prairie, MN: Physical Electronics, 1995.
Calculated Mn(2p3/2) X-ray photoelectron spectra (XPS) of Mn2+, Mn3+, and Mn4+free ions are strikingly similar to Mn(2p3/2) spectra of Mn2+-, Mn3+-, and Mn4+-oxides and oxyhydroxides, indicating that these ions adopt high spin states in MnO, manganite, and birnessite. The Mn...
论文2:Formation of CuMn Prussian Blue Analog Double-Shelled Nanoboxes Toward Long-Life Zn-ion Batteries 图3 Mn2p分峰拟合结果 这篇论文发表在了Angewan上,而且作者中也有不少大牛,说明整体工作是非常好的,我们这里只对XPS部分进行简单的分析。本文中,作者制备了一种CuMn普鲁士蓝类似物,为了表征材料中Mn的...