Finally, we demonstrate that the reason that nature really chose phosphate is due to interplay between two counteracting effects : on the one hand, phosphates are negatively charged and the resulting charge-charge repulsion with the attacking nucleophile contributes to the very high barrier for ...
Why nature really chose phosphate Phosphoryl transfer plays key roles in signaling, energy transduction, protein synthesis, and maintaining the integrity of the genetic material. On the sur... SCL Kamerlin,PK Sharma,RB Prasad,... - 《Quarterly Reviews of Biophysics》 被引量: 145发表: 2013年 ...
These conversion coatings, which can be on steel, aluminum, or most other metals, typically include zinc, manganese, and iron phosphates or chromates. The principle function of these coatings is to improve adhesion of finishes and maximize corrosion resistance. The functionality of conversion ...
This choice is based on the fact that hydrolysis of these anionic molecules is thermodynamically favourable, but occurs only slowly. This kinetic stabilityPratt, Andrew JJournal of CosmologyPratt, A.J. Why Nature chose phosphates over arsenates? J. Cosmol. 2010, 13, 3601-3608....
Why did Nature select phosphate for its dominant roles in biology?. Matthew W. Bowler,,Matthew J. Cliff,Jonathan P. Walthob, et al. New Journal of Chemistry . 2010Bowler, M.W., Cliff, M.J., Waltho, J.P. and Blackburn, G.M. (2010) Why did nature select phosphate for its ...