To do borderless printing, you'll need to adjust the settings in your printer's software. Look for a setting called "borderless printing" or something similar. You may also need to select the correct paper size and type. Does the quality of the image affect the result of borderless printing...
But that enlargement is just movie fiction, not at all real life. Enlarging the original film or a straight-out-of-the-camera digital image might show more detail than otherwise seen, but when a digital image reaches the pixel size limit, all it shows is the pixels (as above). But don...