This provides a momentous opportunity that will affect technological applications in a positive manner. On the basis of its layer-independent properties, this review highlights the weak coupling feature of ReS2 and the emerging applications ranging from energy-related applications to smart devices. The...
That is, the &Dgr;S‡ values were positive and the &Dgr;H‡ parameters closely agreed with bond dissociation enthalpies (BDEs) obtained from DFT calculations. For example, for cyclohexene replacement by pyridine, ejçerimental &Dgr;H‡ and &Dgr;S‡ values were determined to be 19.7 ...
Electron-deficient aromatic π-conjugated molecules are essential for the design of organic analogs ofn-doped semiconductors1, and can serve as light sensitizers for photooxidation and for initiating charge transfer (CT) via hole transduction2. Placing electron-withdrawing substituents or positive charges ...
Finally, the H-score had been obtained by multiplying the staining intensity by the percentage of positive cytoplasmic staining cells (Supplemental Information). Quantitative real-time PCR Total RNA was isolated with Trizol from tumor as well as normal tissue samples collected from each patient and ...
Mass spectra were obtained by MALDI-TOF in the positive ion mode. Synthesis of 5-carboranyl-hexanyl tosylate (2) Into a mixture of 10 g (0.102 mol) of 5-hexyn-1-ol (1) and 100 ml of CH3Cl was added 19.5 g (0.102 mol) of p-toluenesulfonyl chloride followed by 18 ml of ...
Its sterically demanding substituents shield the nucleophilic center, making diethyl ether a better hydrogen bond acceptor in comparison (middle X-ray structure). The high symmetry and the positive (blue) partial charges on the molecular surface are reflected in the right fractal-like model. Details...
Its sterically demanding substituents shield the nucleophilic center, making diethyl ether a better hydrogen bond acceptor in comparison (middle X-ray structure). The high symmetry and the positive (blue) partial charges on the molecular surface are reflected in the right fractal-like model. Details...
Hence, an exothermic event results in a positive heat flow and an endothermic event results in a negative heat flow. The data was analysed using the instrument’s internal software package, and fitted with a 1:1 binding model. Each titration was conducted at least three times, and the ...