Determine the configuration, the number of unpaired electrons, and the ligand field stabilization energy as a multiple of o or T for the complex below using the spectrochemical series to decide, where rele...
(2007) Strong and weak hydrogen bonds in the protein-ligand interface. Proteins;67:128-141.Strong and weak hydrogen bonds in the protein-ligand interface. SK Panigrahi,GR Desiraju. Proteins: Struct Funct Bioinform . 2007Strong and weak hydrogen bonds in the protein-ligand interface. Panigrahi ...
The ligand field photolysis of the three complexes (I) is studied in acidic aqueous solution.doi:10.1002/chin.198748113RICCIERI, P.ZINATO, E.DAMIANI, A.WILEY‐VCH Verlag GmbHCheminformRiccieri P, Zinato E, Damiani A (1987) Inorg Chem 26: 2667 View Article...
Would it be better to use octahedral Ni2+ complexes or octahedral Cr2+ complexes to determine whether a ligand is a strong-field or a weak-field ligand by determining experimentally the number of unpaired electrons? How else could ...
(K64, R77, K100 and R130) create a strong transverse electrostatic field, likely to interact favourably with zwitterionic molecules such as ampicillin (Fig.S6)33,44. Due to our electrophysiological findings, we focused on the extracellular side of the constriction zone as the most probable ...
Panigrahi SK, Desiraju GR (2007) Strong and weak hydrogen bonds in the protein-ligand interface. Proteins: Structure, Function, and Bioinformatics 67: 128-141.Panigrahi SK, Desiraju GR (2007) Strong and weak hydrogen bonds in the protein-ligand interface. Proteins 67:128–141 View Article...
Sarkhel S & Desraju GR (2004) N-H-O, O-H-O, and C-H-O hydrogen bonds in protein-ligand complexes: strong and weak interactions in molecular recognition. Proteins 54, 247-259.Sarkhel S, Desiraju GR (2004) N–H···O, O–H···O, and C–H···O hydrogen bonds in protein...
The binuclear iron complexes (CH 3 CN) 2 Fe 2 (CO) n ( n =7, 6), containing both the strongly back-bonding CO ligand and the weakly back-bonding acetonitrile ligand, have been investigated by density functional theory. The acetonitrile ligands are always found to be terminal in such ...
In general, when free ions are placed in a crystalline environment to form oxides, drastic changes are expected due to the interaction between the neighboring oxygen ions through crystal-field and ligand-field splitting. These two go hand-in-hand, and are especially large in the case of partial...