The compound is an excellent nucleophile, which means it can form bonds with electrophiles by donating an electron pair. It has several industrial applications — it is primarily used to synthesize plant growth regulators, dye leveling agents, tetramethylammonium hydroxide, and choline. 11. Hydrazine ...
A new synthetic protocol for the formation of novel Schiff bases between a weak nucleophile, 2,3-diamino-1,4-naphthoquinone and aldehydes has been developed with addition of hexamethylbenzene (HMB). The driving force for the reaction is the intermolecular CT interaction between HMB and DANQ ...
Interestingly, the dimetal complex is bifunctional in this process, acting as a nucleophile at the nitrogen atoms of the TEhpp ligands, and as an electrophile at the Mo鈥揗o axial bond sites. The protonation requires a novel synergism of these disparate bonding interactions, in which protonation...
The function of the mixed chelate system is to transfer the acetyl group from acetyl phosphate to an acceptor nucleophile via the intermediacy of a triethylenetetramine containing a micellizing side chain and an acetyl accepting nucleophilic group. Through the application of 31 P NMR measurements on...
Basicity‐Engineered Graphite Fluoride Functionalization and Beyond: An Unusual Reaction between Ultraweak Nucleophile and Ultrastrong C?F Bondsaminationenergy‐storage materialgraphene functionalizationgraphite fluoridereductive defluorinationGraphite fluoride-launched graphene functionalization has attracted increasing ...
Takahashi, ONishio, M