where λ denotes the wavelength, and λminand λmaxare the wavelengths at the lower end and the higher end of the spectrum, respectively. The reference spectrum (Supplementary Fig.9, black curve) was measured in the H2O based NMR buffer at 20 °C. To mimic the thermal unfolding condition...
. Moreover, the micro-Raman spectrum shows that the two W present in the peptide sequence are in two distinct environments and that there is no β-sheet network within the three types of assemblies, that is, large nanotubes, small and large crystals (Supplementary Note 4). This information ...
In this work, I describe the measurement of proton-proton dynamics in proteins by means of NMR relaxation experiments.The HSQC-TROSY-based 畏zK NMR experiment constitutes the methodological basis of this dissertation. This experiment measures the K rate for each amide proton, which is the sum of...
Solid-state NMR GIPAW DFT Simulation Visualisation 1. Introduction First-principles calculations of NMR parameters in the solid state are a vital component of the NMR crystallography toolbox, providing a connection between the underlying atomistic structure and the observed NMR spectrum [1], [2]. Su...
1H NMR spectrum of para 8; Figure S13: 13C NMR spectrum of para 8; Table S1: Crystal data and structure refinement for meta 5; Table S2: Bond lengths [Å] and angles [°] for meta 5; Table S3: Crystal data and structure re-finement for ortho 8; Table S4: Bond lengths [Å...
The double membrane structure is essential for proton (H+) gradient formation, which ultimately drives energy generation (adenosine- triphosphate, ATP, molecules). The proton (H+) gradient, and thus ∆m, originates from the accumulation of H+ in the intermembrane space (IMS) via active ...
Molecular and Cellular Insights: A Focus on Glycans and the HNK1 Epitope in Autism Spectrum Disorder. October 13, 2023 [ MEDLINE Abstract ] Comparative Analyses of Chloroplast Genome Provide Effective Molecular Markers for Species and Cultivar Identification in Bougainvillea. October 13, 2023 ...
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4. Structural evolution of bR: resolving a revolving photocycle 5. The primary proton transfer event and vectoriality of the pump 6. Overview of the structural mechanism Acknowledgements ReferencesShow full outline Cited by (178) Figures (11) Show 5 more figuresBiochimica...
NMR: nuclear magnetic resonance POX: phenol oxidase PSM: peptide-spectrum match VP: versatile peroxidase References Kersten P, Cullen D. Extracellular oxidative systems of the lignin-degrading basidiomycete Phanerochaete chrysosporium. Fungal Genet Biol. 2007;44:77–87. Article CAS Google Scholar ...