Herein we present a novel metal-organic framework (UTSA-16 (Zn)), where cobalt in the framework is replaced by zinc via microwave irradiation, with significantly improved stability in humid air and acid gases and better selectivity (CO2/N-2) than the original Co-containing framework. The ...
Poly (oxyethylene methacrylate) POEM (poly (ethylene glycol) methyl ether methacrylate, Mn = 500 g mol−1), tetrahydrofurfuryl methacrylate (THFMA), potassium hydroxide (KOH), cobalt (II) acetate, citric acid, and diethyl ether were purchased from Sigma-Aldrich. Poly (1-(trimehthylsilyl-1-...