ChemInform Abstract: A New Type of Carbon-Carbon Bond Cleavage of 3-Methyl-2-(2-oxoalkyl)-2-phenylbenzothiazolines (I) to Ketones Under Acidic Conditions.cleavage reactions, decomposition reactions, pyrolysisbenzothiazole derivativesketones (benzene compounds...
A Novel Type of Carbon-Carbon Double Bond Cleavage of 1,1-Disubstituted Alkenes on a...Examines a carbon-carbon double bond cleavage of 1,1-disubstituted alkenes on a triruthenium polyhydrido cluster. Applicability to the functionalization of saturated carbons; Activation of organic substrates on ...
Biosynthesis of Enfumafungin-type Antibiotic Reveals an Unusual Enzymatic Fusion Pattern and Unprecedented C鈥揅 Bond Cleavage 来自 ACS 喜欢 0 阅读量: 3 作者:ZhiQin Cao,GaoQian Wang,Rui Luo,YaoHui Gao,JianMing Lv,ShengYing Qin,GuoDong Chen,Takayoshi Awakawa,XueFeng Bao,QingHua Mei ...
Selective C—O bond cleavage of oxidized lignin and lignin-type materials into simple aromatic compoundsA method to cleave C—C and C—O bonds in β-O-4 linkages in lignin or lignin sub-units is described. The method includes oxidizing at least a portion of secondary benzylic alcohol groups...
This paper describes the formation of new platinacyclic complexes derived from the phosphine ligands P i Pr2Xyl, PMeXyl2, and PMe2Ar (Xyl=2,6-Me2C6H3 and A... J Campos,L Ortega‐Moreno,S Conejero,... - Chemistry - A European Journal 被引量: 9发表: 2015年 PC bond cleavage of (...
& Lory, S. Amino acid substitutions in pilin of Pseudomonas aeruginosa. Effect on leader peptide cleavage, amino-terminal methylation, and pilus assembly. J. Biol. Chem. 266, 1656–1664 (1991). CAS PubMed Google Scholar Macdonald, D. L., Pasloske, B. L. & Paranchych, W. ...
bond in 45-kDa single-chain urokinase-type plasminogen activator (scu-PA) and in its two-chain (tcu-PA) derivative, yielding a 17-kDa NH2-terminal domain comprising the u-PA receptor (u-PAR) binding site and a 32-kDa COOH-terminal moiety containing the serine proteinase domain of u-PA....
The Schmidt rearrangement, a reaction that enables C-C or C-H σ bond cleavage and nitrogen insertion across an aldehyde or ketone substrate, is one of the most important and widely used synthetic tools for the installation of amides and nitriles. However, such a reaction frequently requires ...
With Ru3(CO)12, carbon–sulfur bond cleavage occurs to give the tetranuclear clusters [MRu3(CO)14(μ4-S)(μ-κ1:η1-pym)] (14–15) bearing both the extruded sulfur and the heterocyclic ring. The molecular structures of1–7,10and12have been established by X-ray diffraction allowing ...
The three pRSET vectors contain a T7 RNA polymerase promoter, a hexahistidine metal-binding domain, and an enterokinase cleavage site at the 5′ end of the polycloning site. The plasmids were used to express recombinant proteins in E. coli strain INVαF′ (Invitrogen) as described (30). ...