The turnover-limiting step for the asymmetric allylic oxidation is the formation of chiral catalyst-...
In ecosystems with well aerated soils, nitrification proceeds very fast and supply of NH4+ appears to be the rate limiting step. Nitrates can be lost via denitrification, controlled primarily by availability of carbon. In flooded rice ecosystems, denitrification rate is determined by NO3 supplying ...
We conclude that formation of the T-AT complex is the primary rate-limiting step in catalytic turnover and that this reaction is accompanied by a change in conformation of the AT component resulting in facile dissociation.doi:10.1016/0014-5793(86)81011-0S T Olson...