This paper describes a series of bimetallic compounds derived from the starting complexes [Ni(tdpme)Cl2] and [Pt(tdpme)Cl2] [where tdpme = 1,1,1-tris(diphenylphosphinemethyl) ethane, MeC(CH2PPh2)3] upon reaction with Ph3SnCl and NaBH4, as well as with SnCl2. In the first case, a...
别名 三(甲基苯)乙烷 | 1,3-二(二苯基膦基)-2-(二苯基膦基)甲基-2-甲基丙烷 英文别名 Triphos | NSC158168 | NSC-158168 | [3-(diphenylphosphanyl)-2-[(diphenylphosphanyl)methyl]-2-methylpropyl]diphenylphosphane | SY066971 | Triphos | [2-[(Diphenylphosphino)methyl]-2-methyl-1,3-propaned...
791-28-6 三苯基氧化膦(月产百吨) riphenylphosphine oxide171596-29-5 他达拉非 Tadalafil1609405-34-6 N-乙基他达拉非 N-Ethyl tadalafil171596-36-4 去甲基他达拉非 DeMethyltadalafil385769-84-6 氨基他达拉非 Amino Tadalafil171752-68-4 他达拉非N-2中间体 (1R,3R)-9H-PYRIDO[3,4-B]INDOLE...
Crystal structure of ( 1α,8α,9β,12β)-1,8-diphenyl-13- oxatetracyclo-[6.4.1.02,7.09,12]trideca-2,4,6,10-tetraene, C24H18O Crystal structure of N,N’-ethylene-bis(1,3-dimethyl-5-pyrazolethiolatoiminomethyl) copper(II), C14H18CuN6S2 Crystal structure of of N,N’-1,3-di...
1,1,1-tris-(4-acetyl-phenyl)-ethane is added. The solution loses its color. The mixture is heated under reflux for 24 hours and the precipitate (unreacted triketone and phosphine oxide) is filtered off when the solution is at room temperature. It is washed with diethyl ether and then ...
Crystal structure of bromo-(1,10-phenanthroline-N,N̸)-(4-(N,N-dimethylamino)phenyldiphenylphosphine)-copper(I),CuBr(CHN)(CHNP) Crystal structure of 1-ferrocenyl-4-phenyl-1,3-butadiyne, (CH)Fe(CH) Crystal structure of bis(2,2′-bipyridine-N,N′)dibromomanganese(II), MnBr(CHN) Ref...
The syntheses of two new tris-phosphine cyclooctadiene (COD) iridium complexes are reported. In the first, [Ir(COD)(PMe 3 ) 3 ]Cl路0.5H 2 O, the geometry about iridium is square pyramidal. In the second, [Ir(COD)(tripod)][BF 4 ] [tripod = 1,1,1-tris(diphenyl-phosphinomethyl)...
Optical properties of Ag(tripod)X with tripod = 1,1,1-tris(diphenyl-phosphinomethyl)ethane and X − = Cl − and I −: Intraligand and ligand-to-ligand charge transferElectronic spectraLuminescenceCharge transferSilverPhosphine complexes
Molybdenum(0)‐N2 Complexes Supported by the Tripod Ligand 1,1,1‐Tris(Diphenyl‐Phosphinomethyl)Ethane: Steric Influence on the Coordination of Mono‐ and Diphosphine ColigandsMolybdenumNitrogenP ligandsNitrogen fixationTripodal ligandsThe syntheses and physicochemical properties of the three dinitrogen ...
Cationic cobalt(I) complexes with the general formula [(triphos)Co(L)]Y (triphos 1,1,1-tris(diphenylphosphinomethyl) ethane; L 1,3-butadiene, isoprene, 1,3-cyclohexadiene, 1,3,5-cycloheptatriene, 1,3,5,7-cyclooctatetraene, phenylacetylene, diphenylacetylene) have been obtained by reaction ...