The M2(S-mes)6 compounds are the first examples of compounds containing triple bonds between molybdenum and tungsten atoms supported exclusively by thiolate ligands. Pertinent bond distances () and angles (°) are: M M = 2.228(1) (Mo), 2.312(2) (W); M S = 2.325(2) (Mo), 2.32(1)...
This paper deals with design specifications and monitoring of batch extractors for the two examples mentioned above. The effects of initial solid feeding mass and final solid concentration on extractor volume were illustrated as design results.doi:10.1002/anie.199010321...
Write the molecular formula for a straight-chain alkyne with one triple bond and six carbon atoms. Write the molecular formula for a straight-chain alkyne with one triple bond and seven carbon atoms. What does the structural formula for 2-octene, which has a dou...
Homometallic examples are found in spectroscopic or fullerene-confined species, and heterometallic variants exhibiting a polar covalent σ bond supplemented by up to two dative π bonds are more prevalent. Hence, securing polar covalent actinide double and triple metal–metal bonds under normal ...
In all of these reactions, the carbons joined by the triple bond in the original alkyne remain bonded to each other in the resultant transition metal complex. This paper considers the first examples of a third type of reactions of metal carbonyls with alkynes in which the C=C of the ...
organo-transition-metal compoundsChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original ...
Although some p-block element compounds could also react with CO 24–38 or isonitriles28,39,40, the strongest s-bond among the three bonds in a triple bond remained intact in all cases. On the other hand, chemistry containing Lewis-base adduct of sp2–sp3 diborane(4) compounds has been...
ChemInform Abstract: THE MOLYBDENUM-MOLYBDENUM TRIPLE BOND. 15. COMPOUNDS WITH CHAINS OF METAL ATOMS HAVING M-M SINGLE AND TRIPLE BONDS: M2(M′(M′ME3)3)2(... MH Chisholm,HT Chiu,K Folting,... - 《Chemischer Informationsdienst》 被引量: 0发表: 1985年 ChemInform Abstract: Equilibration ...
Learn what a phase diagram is. Discover the importance of the triple point and critical point in a phase diagram, and study examples of phase diagrams. Updated: 11/21/2023 Table of Contents What Is a Phase Diagram? Critical Point on a Phase Diagram What Is a Triple Point? Cri...
Transition metal reagents and catalysts are generally effective to cleave all three bonds (one σ and two π) in a triple bond despite its high bonding energy. Recently, chemistry of single-bond cleavage by using main-group element compounds is rapidly being developed in the absence of transition...