Detection of bis(triphenylphosphine)palladium(II) dichloride by electrospray ionization quadrupole ion trap mass spectrometry using different imidazolium salts as the charge carrier has been reported. It is employed as catalyst for the Heck reaction medium. 8.6 Flammability and Explosibility Nonflammable...
6. NMR Spectrum13C NMR : in CDCl3 1H NMR : 400 MHz in CDCl3 1H NMR : 90 MHz in CDCl3 IR : KBr disc IR : nujol mull Mass Mass spectrum (electron ionization) UV/Visible spectrum 7. Synthesis Route3878-45-3Total: 85 Synthesis Route ...
However it can always be prepared freshly by mixing Pd(NO3)2 (2mmols) and PPh3(2mmols) in hot *C6H6 when vigorous evolution of nitric oxide occurs and a solid mass separates. This is collected and crystallised from EtOH. Its cryoscopic constant in *C6H6 (at 0.601g/20mL) corresponds to ...
with triphenylphosphine, rhodium salt (1:2:1); Carbonyl dichloride; CARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE; CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)RHODIUM(I); Chloro(oxomethanidyl)rhodium(1+) - triphenylphosphine (1:2); CHLOROCARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM (I); Chlorocarbonylbis(...