A qualitative characterization of the transition state is presented in terms of a reaction coordinate diagram that is defined by the structure—reactivity parameters.Biochemistry
Onset Dynamics of Phase Transition in Ar7 The phase transition of Ar7, especially its onset dynamics, is analyzed from various points of view. A reaction path diagram among all the quenched structu... N Shida - John Wiley & Sons, Inc. 被引量: 4发表: 2005年 CATALYST COMPOSITION FOR OLEFI...
The source of the wing emission has been examined in some detail. The earlier proposal [J. Chem. Phys.73, 5895 (1980)] that the wing comprises the emission spectrum of transition states FNaNa* which exist as the reaction products are in the process of separating, is in best accord with...
These states are also known as OR-states because when running, the instance must be in exactly one of these states, no more and no less. Three key properties of states are entry actions, exit actions, and internal transitions. Entry actions are a list of actions that are executed whenever...
Finally, a lower bound on the reaction probability is derived; this bound complements the upper bound provided by transition state theory and is ... E Pollak,P Pechukas - 《Journal of Chemical Physics》 被引量: 133发表: 1979年 Phase Transitions in the Spin-Half J_1--J_2 Model The coup...
(TM = transition metal) Goodenough in fact pointed out as early as 200132that Pr is the only rare-earth or lanthanide A-site ion likely to have 4 fstates near the Fermi energy. In the RCoO3series this has been verified through density functional theory (DFT) calculations33, and ...
Ferroic materials with coexisting states of comparable energy typically exhibit extraordinary responses to external stimuli, such as giant electrocaloric effect1,2, ultrahigh energy storage density3,4,5, colossal magnetoresistance6, and giant magnetostriction7. This feature can be exploited in poled ferroe...
In order to obtain simple relationships between kinetics and thermodynamics, the free energy barrier for a complex system such as a protein must occur in a region of high density of states. As one descends into the funnel, the density of configurations diminishes until a so-called glassy regime...
,D.,Anderson,A.,R. 摘要: The isovector 0+ to 0- transition in the 16O(p,n)16F (g.s.) reaction was studied at 79 MeV. Differential cross sections were extracted for the transitions to the low-lying complex of 0-, 1-, 2-, and 3- states in 16F at 12 laboratory angles from ...
2G, H. The diagram showed that BrdU/IdU/I + B shared 25.2% (8240/32655) in CO peaks, but only 19.3% (7243/37575) in OC peaks. Additional file 1: Fig. S2E illustrates that a larger fraction of peaks in CO are located in the promoter regions. In conclusion, the function of ...