Transition-state stabilization as a measure of the body efficiency of antibody catalysis.Describes a study which used transition-state theory in the quantitative analysis of the scope and limitations of antibody catalysis. Prediction of rate accelerations based on the ratio of equilibrium binding ...
Impaired glucose tolerance ( IGT ) is atransition statebetween being healthy and having diabetes. 葡萄糖耐量减低 ( IGT ) 是健康状态与糖尿病中间的过渡阶段. 互联网 The relationship between the aromatictransition statetheory and Woodward - Hoffmann generalization are also discussed. ...
Transition state theory suggests that enzymatic rate acceleration (kcat/knon) is related to the stabilization of the transition state for a given reaction... C Peter,Tyler,A Erika,... - 《Journal of the American Chemical Society》 被引量: 30发表: 2007年 加载更多来源...
Transition state mimics bind tightly to enzymes by capturing a fraction of the binding energy for the transition state species. The identification of numerous transition state inhibitors supports the transition state stabilization hypothesis for enzymatic catalysis. Advances in methods for measuring and ...
reactants, transition states, and confining voids to chemical reactivity and selectivity.Confinement mediates enthalpy–entropy compromises that determine the Gibbs free energies of transition states and relevant reactants; these activation free energies determine turnover rates via transition state theory....
Comments on Two Derivations of a Transition-State Theory of Chemical Reactions 来自 Semantic Scholar 喜欢 0 阅读量: 7 作者:BC Eu,J Ross 摘要: Scitation is the online home of leading journals and conference proceedings from AIP Publishing and AIP Member Societies关键词: Chemical reaction theory ...
The importance of key residues to the activity of the cAMP-dependent protein kinase catalyzed phosphoryl transfer and to the stabilization of the transition state of the reaction has been investigated by means of the fragment molecular o... Öberg, Helena,T Brinck - 《Physical Chemistry Chemical...
Table 2 The structural parameters calculated by the Birch–Murnaghan equation of state. Full size table The structural phase transitions of Li5MoH11are presented by the relative enthalpy, which is obtained from the difference between the enthalpy calculated and that of the P63cm structure, as a ...
social–environmental movements that emerge to challenge inequitable outcomes (Robbins, 2004; Martinez-Alier et al., 2010). Political science theory is also relevant, including public choice (Buchanan et al., 1980), evolutionary policy (van den Bergh and Kallis, 2009) and state regulation theories...
According to the transition state theory, the rate of a reaction is given by $$r={\nu }_{0}{e}^{-\frac{{\rm{\Delta }}{G}^{\ne }}{{k}_{B}T}},$$ (1) where v 0 is the pre-exponential factor, reflecting the thermal vibration frequency of the system, with an order of...