Transition metal-catalyzed arylation of unactivated C(sp3)-H bonds. Chem. Soc. Rev. 40, 4902-4911 (2011).O. Baudoin, Transition metal-catalyzed arylation of unactivated C(sp3)-H bonds. Chem. Soc. Rev. 40, 4902-4911 (2011). Medline doi:10.1039/c1cs15058h...
Transition-metal-promoted C(sp2)−H allyation This particular part is basically the heart of this review, as it showcases the unprecedented enlargement of TM-catalyzed C(sp2)−H allylation reactions. A diverse array of allylating reagents have been explored for this transformation, which, base...
TransitionMetal-Catalyzed：过渡金属催化
aTransition metal-catalyzed polycondensation reaction is the fifth route in the polycondensation reactions used to synthesize main-chain ferrocene-based polymers. 转折金属摧化的缩聚反应是第五条路线在用于的缩聚反应综合主要链子基于ferrocene的聚合物。[translate]...
From C(sp2)-H to C(sp3)-H: systematic studies on transition metal-catalyzed oxidative C-C formation. In this tutorial review, we will summarize our recent efforts in transition metal-catalyzed oxidative couplingviaC–H functionalization of aromatic, benzyl......
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Incorporation of a transition metal (for example, Pt, Au, Pd) as vapour-deposited nanoparticles or solution-processable organometallic complexes (for example, Pd2(dba)3) catalyses the reaction, as assessed by experimental and theoretical evidence, enabling greatly increased η in a much shorter ...
Transition metal-catalyzed reactions including carbonylations, hydrovinylations and hydrogenations have been applied in the synthesis of alpha-(3-benzoylphenyl)propanoic acid (Ketoprofen). 3-Vinylbenzophenone was obtained from 3-bromobenzophenone by a Pd-catalyzed Heck coupling reaction. Pd-catalyzed carb...
Rapid, direct transition metal-catalyzed C-P(III) cross-coupling reactions were performed by microwave dielectric heating, employing diphenylphosphine and aryl halides/triflates as substrates. Depending on the specific aryl halide/trifla... A Stadler,CO Kappe - 《Organic Letters》 被引量: 0发表:...
Transition-metal-catalyzed asymmetric allylic substitution reactions have been demonstrated to be powerful methods for enantioselective formation of C-C and C-X (X = O, N, S, etc.) bonds. However, the scope of these processes has been explored mainly using soft carbon nudeophiles, some hard ...