The very interesting photochemical properties of a new class of ruthenium complexes with NHC-carbene containing potential bridging ligands are discussed. These complexes can bind catalytic metal centers at the NHC sphere. The so formed photochemical devices are active photocatalysts for hydrogen evolution....
The attempted synthesis of the corresponding nickel complex furnished single crystals of the composition [{fc(NHCyp)2}Cl(NiCl3)]; X-ray diffraction analysis afforded the first crystal structure of the [Ni2Cl6]2– anion.doi:10.1002/ejic.201701073Kristof...
This report provides a critical overview of recent developments in the use of N-heterocyclic carbenes (NHCs) with transition metals. For these NHC ligand-containing complexes, an analysis is focused on their performance and scope in catalysis. There is also an increasing interest in the role of ...
The synthesis and structure of several new early transition metal (Ti, Zr, Hf, and V) NHC complexes supported by one or two IMes ligands is described. Reaction of M(NMe2)4 with IMes.HCl gives compounds VCl2(NMe2)(IMes)2 (2), and MCl2(NMe2)2(IMes) (M = V (3), Zr (4), ...
The present paper comprehensively reviews group 3–7 metal NHC complexes reported since 2014, with emphasis on their current applications and fundamental reactivity. Thanks to NHC stabilization, such metal complexes have witnessed significant and diversified developments, essentially in the area of homogeneo...
88. Dependence of Spin State, Structure, and Reactivity of [FeII(L) ('N<inf>H</inf>S<inf>4</inf>')] Complexes on the Coligand L (L = CO, N<inf>2</inf>H<inf>2</inf>, N<inf>2</inf>H<inf>4</inf>, NH<inf>3</inf>, Pyridine, NHCH<inf>3</inf>NH<inf>2</inf>...
Syntheses of the first heteroleptic N-heterocyclic carbene (NHC)–phosphane platinum(0) complexes and formation of the corresponding Lewis acid–base adducts with aluminum chloride is reported. The influence of N-heterocyclic carbenes on tuning the Lewis basic properties of the metal complexes was jud...
the reaction sequence leading to the metal-NHC bond formation using the weak base route.In addition to the synthesis of transition metal complexes, their ... T Scattolin,A Simoens,CV Stevens,... - 《Trends in Chemistry》 被引量: 0发表: 2022年 Continuous Flow Synthesis of Metal-NHC (NHC...
44 In addition, structures of iron-aryl complexes that contain NHC ligands,45,46 nitrogen-donor ligands,47 pincer ligands48 and Cp⁎ ligands49–51 have also been reported. In this chapter, recent examples of iron-alkyl and iron-aryl complexes are described with a focus on those that have ...
N-Heterocyclic carbene transition metal complexes in light emitting devices In this minireview, a state of the art of the NHC transition metal complexes applied in two different modern technologies for lightening applications, name... JLGS Elie - 《Polyhedron the International Journal for Inorganic &...