It concerns the a-type nu16 absorption band of gaseous trans-1,2-dichloroethane at 1232 cm-1, which we have recorded using a Fourier transform interferometer, under room temperature and jet-cooled experimental conditions. The rotational analysis of the almost diatomic-like prominent R and P ...
Effect of pressure on molecular conformations. Trans–gauche equilibrium of 1,2-dichloroethane and 1,2-dibromoethane.Taniguchi, Y.; Takaya, H.; Wong, P.; Whalley, E. Effect of Pressure on Molecular Conformations. Ii. Trans-Gauche Equilibrium of 1,2-Dichloroethane and 1,2-Dibromoethane. J...
In chlorinated solvents, complexes I undergo a slow reversible dimerization into the binuclear derivatives [PdCl(μ-R N)(PPh 3)] 2 (II) (μ-R N = C 2, N 1-bridging ligand). From the 31P NMR spectra in 1,2-dichloroethane the following dissociation constants were obtained: 1.9 mol 1...
ChemInform Abstract: SUBSTITUENT DIRECTED META PHOTOCYCLOADDITION OF TRANS‐1,2‐DICHLOROETHANE TO BENZONITRILEphotochemistry, radiation chemistry, chemoluminescenceThe presence of a dimethylsilylene unit at the 4-position of 5-phenylpent-1-ene bichromophores induces high selectivity into their intramolecular ...
It contains the Chapter 'Volumetric Properties of the Mixture trans-1,2-Dichloroethene C 2 H 2 Cl 2 + C 2 H 4 Cl 2 1,2-Dichloroethane (VMSD1211, LB4434_V)' providing data from direct low-pressure dilatometric measurement of molar excess volume at variable mole fraction and constant ...
SUBSTANCE: method involves dehydrochlorination of 1,1,2-dichloroethane. The process is carried out at 200-280 C and at atmospheric pressure in the presence of heterogeneous catalyst on the base of FeCl3 and γ-Al2O3. Concentration of 1,1,2-trichloroethane in nitrogen is 0.5 10-3-3•10-...
Yield of cis-1,2-dichloroethane and trans-1,2-dichloroethane is 33.0-65.5 mol % and 19.3-32.4 mol %, respectively. EFFECT: improved efficiency of the method. 5 tblBELOKOPYTOV YURIJ VASILEVICHKONOVALOVA NADEZHDA DMITRIEVNASERGUCHEV YURIJ ALEKSEEVICH...
It provides vapor-liquid equilibrium data for State: Two-component system, single-phase liquid or two-phase liquid-liquid in equilibrium with vapor Pure component 1: C 2 H 4 Cl 2 1,2-Dichloroethane [107-06-2], liquid in equilibrium with vapor Pure component 2: C 2 H 2 Cl 2 trans-1...
azeotropic mixtures of 1,1,1,2,3,4,4,5,5,5-decafluoropentane (HFC-43-10mee) and trans-1,2-dichloroethylene, cis-1,2-dichloroethylene or 1, 1-dichloroethane. These azeotropic mixtures are useful as cleaning, blowing agents for polyolefins and polym茅thanes, cooling agents, aerosol ...
mixtures of 1,1,1,2,3,4,4,5,5,5 - d u00e9cafluoropentane azeotropes (hfc-43-10mee) and trans 1,2 dichloroethylene cis 1,2 dichloroethylene, or 1,1 - dichloroethane.these mixtures azeotropes are useful as cleaning agents, blowing agents for polyolefins and polym u00e9thanes, cooling ...