Herein, an efficient and high-yield method was proposed for the preparation of ultra-thin 2D Mo2C via Na2CO3-assited carbothermal reduction of 2H–MoS2. It was found that 2H–MoS2 can be completely carbonized to Mo2C at a MoS2:Na2CO3:C molar ratio of 2:4.2:11 at 850 °C for 2 h. ...
The photo-reversible property of azobenzene has been the basis for smart materials with remote-controllable applications in switchable delivery systems, rewritable hologram films, and optically active fibers17–19. The main objective of this study is to fully utilize the different phot...
Graphene: Understanding its structure, synthesis, and functionalization 2024, 2D Materials: Chemistry and Applications Part 1 Aptameric Metal-Organic Framework Nanobiosensor 2024, ACS Applied Nano Materials A porous organic polymer nanosphere-based fluorescent biosensing platform for simultaneous detection of ...
conductivities for energy storage devices.35 The topochemical approach for 2D polymer synthesis is advantageous over solution-phase synthesis as it enables thorough structural elucidation and gives ordered 2D polymers.36 For the top- ochemical synthesis of 2D polymers, monomers with multi...
Topochemical Synthesis of Two‐Dimensional Transition‐Metal Phosphides Using Phosphorene Templatesblack phosphoruselectrochemistrytopochemistrytransition-metal phosphidestwo-dimensional materialsTransition‐metal phosphides (TMPs) have emerged as a fascinating class of narrow‐gap semiconductors and electrocatalysts. ...
Topochemical Synthesis of Two-Dimensional Transition-Metal Phosphides Using Phosphorene Templatesblack phosphoruselectrochemistrytopochemistrytransition-metal phosphidestwo-dimensional materialsTransition-metal phosphides (TMPs) have emerged as a fascinating class of narrow-gap semiconductors and electrocatalysts. ...
The method developed for the synthesis of 2D TMPs thus provides new insights into the future development of other non﹍ayered 2D materials.doi:10.1002/ange.201911428John Wiley & Sons, LtdAngewandte Chemie
However, the large-scale synthesis of ultrathin 2D materials with controllable thickness remains a tremendous challenge. Herein, we adopt an efficient topochemical synthesis strategy, employing a confined reaction space to fabricate ultrathin 2D Sn4P3 nanosheets in large-scale. By carefully adjusting ...
Topochemical synthesis of monometallic (Co2+-Co3+) layered double hydroxide and its exfoliation into positively charged Co(OH)2 nanosheets. Angew. Chem. 120, 92-95.Topochemical synthesis of monometallic (Co2+-Co3+) layered double hydroxide and its exfoliation into positively charged Co(OH)2...
Among the promising synthetic techniques, topochemical approaches have afforded the platform for widening the extent of novel 2D materials. Notably, the synthesis of binary layered materials is considered as a major scientific breakthrough after the synthesis of graphene as they exhibit a wide spectrum...