M. Cho, “Trimethylsilyl Isothiocyanate (TMSNCS): An Efficient Reagent for the One-Pot Synthesis of Mercapto-1,2,4-Triazoles,” Tetrahedron Letters, Vol. 53, No. 39, 2012, pp. 5238-5242. doi:10.1016/j.tetlet.2012.07.054D. R. Guda, T. J. Wang and H. M. Cho, "Trimethylsilyl ...
The versatility of trimethylsilyl isothiocyanate (TMSNCS) as a reagent is impressive, especially in heterocycle synthesis. TMSNCS is also commonly used in reactions of thiocyanation and isothiocyanation. The advantages of TMSNCS are moderated toxicity, chemical stability, high tolerance with other funct...
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D. R. Guda, T. J. Wang and H. M. Cho, "Trimethylsilyl Isothiocyanate (TMSNCS): An Efficient Reagent for the One-Pot Synthesis of Mercapto-1,2,4-Triazoles," Tetra- hedron Letters, Vol. 53, No. 39, 2012, pp. 5238-5242. doi:10.1016/j.tetlet.2012.07.054...
Non-catalyzed nucleophilic ring opening reactions of aziridines by tmsncs and synthesis of thiazolidine-2-iminesAziridines are excellent substrates for the addition of various nucleophiles. This constitutes a general method for the synthesis of various 2-substituted amines.[1] The reaction is highly ...
Yasuhiro FunahashiAmerican Chemical SocietyDesymmetrization of meso-aziridines with TMSNCS using metal salts of novel chiral imidazoline-phosphoric acid catalysts. S.Nakamura,M.Ohara,M.Koyari,M.Hayashi,K.Hyodo,N.R.Nabisaheb,Y.Funahashi. Organic Letters . 2014...