Polymerization of (implied by)-caprolactone (CL) initiated with tin(II) octoate (tin(II) 2-ethylhexanoate, (Sn(Oct)_2)) in the presence of butyl alcohol (BuOH) or water and conducted in tetrahydrofuran (THF) as a solvent at 80deg C was studied using MALDI-TOF mass spectrometry. ...
Sn(II)2ethylhexanoate (SnOct2) was reacted with 2 equiv of benzyl alcohol at 20 °C, and a liberation of octanoic acid in a rapid equilibration was found. ... HR Kricheldorf,I Kreiser-Saunders,A Stricker - 《Macromolecules》 被引量: 770发表: 2000年 The basic properties of poly(lactic...
Tin (II) bis(2-ethylhexanoate) Tin (iv) chloride (1:4) Tin 2-ethylhexanoate TIN 770 Tin bis(2-ethylhexanoate) Tin chloride Tin chloride (SnCl2) Tin chloride (SnCl2) dihydrate Tin Chloride (sncl4) Tin chloride (SnCl4) (8CI)
Kinetics of the polymerisation of 蔚-caprolactone and L,L-dilactide initiated with tin(II) 2-ethylhexanoate (tin octoate (Sn(Oct)2)) and carried out in the presence of 2,6-di-tert-butylpyridine (1) and/or 1,8-bis(dimethylamino)naphthalene (2), in THF as the solvent, at 80掳C was...
Kinetics of the polymerisation of ε -caprolactone and L , L -dilactide initiated with tin(II) 2-ethylhexanoate (tin octoate (Sn(Oct) 2 )) and carried out in the presence of 2,6-di- tert -butylpyridine ( 1 ) and/or 1,8-bis(dimethylamino)naphthalene ( 2 ), in THF as the solvent...
Sn(II)2ethylhexanoate (SnOct2) was reacted with 2 equiv of benzyl alcohol at 20 °C, and a liberation of octanoic acid in a rapid equilibration was found. ... HR Kricheldorf,I Kreiser-Saunders,A Stricker - 《Macromolecules》 被引量: 770发表: 2000年 Calcium methoxide initiated ring-open...
A series of model reactions between pure Sn(II) 2-ethylhexanoate (SnOct2) and primary alcohols was studied. At room temperature a rapid and reversible exchange between alcohol and octanoic acid was observed. At higher temperatures (studied up to 180 °C) an esterification yielding alkyl octoate...
A series of model reactions between pure Sn(II)) 2-ethylhexanoate (SnOct(2)) and primary alcohols was studied. At room temperature a rapid and reversible exchange between alcohol and octanoic acid was observed. At higher temperatures (studied up to 180 degrees C) an esterification yielding ...