Three inorganic–organic hybrid compounds based on Keggin polyoxometalate and transition metal complexes: crystal structures and electrochemical propertiesInorganicorganic hybridsPolyoxometalatesElectrochemical propertiesPolyoxometalate (POM)-based coordination polymers, [Cu(L)2][SiW12O40]center dot 4py center dot...
01. THE CLASSIFICATION OF INORGANIC COMPOUNDS The Classes of CompoundsThousands and tens of thousands of compounds are known to the chemist today. It would be impossible to learn properties and behavior of even a fraction of this number if it had to be done on the basis of individual ...
Trinitrotoluene (TNT) and nitrobenzene (NB) are examples of nitro aromatic compounds commonly found in explosives and are highly toxic environmental pollutants. Therefore, their rapid detection is a priority in both security screening efforts and in the monitoring of the environment. Similarly, there ...
Three new hybrid inorganic–organic compounds of silver(I), Ag2(2,6-nds), 1, lead(II), [Pb(2,6-nds)·H2O]n, 2 and copper(II), [Cu(phen)3](2,6-nds)·11H2O, 3, have been synthesized by reacting appropriate reactants in aqueous medium. All the three compounds were characterized...
All first-principles calculations were performed using CIF structure files with the experimental lattice parameters, which can be obtained from the Inorganic Crystal Structure Database (ICSD)107 using the accession numbers provided in SN 8. Code availability The spin-resolved tight-binding and (nested...
e., they contained no interstitial atoms in the center of the cluster polyhedron. However, subsequent synthetic studies led to the discovery of clusters containing interstitial transition metals. Examples of structurally characterized such clusters based on 10-vertex outer polyhedra include the anionic ...
Unfortunately, restriction of commercial BDE mixtures has not led to an overall reduction in the application of FRs, but rather to a shift towards the use of alternative FRs, including emerging FRs and some examples are hexabromobenzene (HBB), pentabro-moethylbenzene (PBEB), decabromodiphenyl etha...
Covalent organic frameworks, cross-linked crystalline polymers constructed from rigid organic precursors connected by covalent interactions, have emerged as a promising class of nanoporous materials owing to their highly desirable combination of attribut
Kelly DP, Shergill JK, Lu WP, Wood AP: Oxidative metabolism of inorganic sulfur compounds by bacteria. Antonie Van Leeuwenhoek. 1997, 71: 95-107. 10.1023/A:1000135707181. CAS Google Scholar Ingledew WJ: Thiobacillus ferrooxidans. The bioenergetics of an acidophilic chemolithotroph. Biochim Biophys...
The compounds are rare examples of alkoxide-bridged {Dy2} complexes and display capped square antiprism coordination geometry around each Dy(III) ion. Changes in the ligand field environment around the Dy(III) ions brought about through variations in the ligand donors can be gauged from the ...