However, the thiol-ene reaction has recently attracted researchers in other areas of synthesis due to the recognition of its ‘‘click’’ characteristics, vide infra. There are several features associated with the thiol-ene reaction that make it a particularly ...
然后通过研究硫醇功能化CNC与丁晴橡胶基体之间的界面相容性和相互作用,讨论了纳米复合材料在梯度硫醇化下的热性能和力学性能,并通过相互作用研究揭示了其增强机理。这一研究成果以题为“Covalent-bond-forming method to reinforce rubber with cellulose nanocrystal based on the thiol-ene click reaction”发表于Composit...
然后通过研究硫醇功能化CNC与丁晴橡胶基体之间的界面相容性和相互作用,讨论了纳米复合材料在梯度硫醇化下的热性能和力学性能,并通过相互作用研究揭示了其增强机理。这一研究成果以题为“Covalent-bond-forming method to reinforce rubber with cellulose nanocrystal based on the thiol-ene click reaction”发表于Composit...
通过thiol-ene反应可以成功得制备功能化聚硅氧烷,该反应一般在8-10min内反应完毕、 反应产率高(>90%)、不需要惰性气体保护、羧基等活性基团不影响反应的进行,符合 Click反应的特点,可以做为一种制备功能化聚硅氧烷的有效方法。 关键字:巯烯反应,点击反应,功能化聚硅氧烷 ...
最近发展的光催化策略也可以在温和条件下得到Thiol-Ene反应的产物.随着氘代药物的发展,氘代硫醚类化合物的合成已经成为一个新的研究重点,然而,目前合成氘代硫醚类化合物的策略存在着氘源昂贵,操作繁琐等不足.为了改善这一情况,使用重水作为氘源和反应介质,在温和的条件下,通过Thiol-Ene反应合成了β-氘代硫醚类化合物...
Diallyl eugenol(2A-EU)and tetrathioglycoluril(TMGU)were prepared from eugenol and glycoluril,respectively. A series of thiol-ene UV curable coatings was prepared by adjusting n(2A-EU)∶n(TMGU), and their heat resistance,curin
Superhydrophobic PA66 was obtained with plant derived phenols by thiol-ene click chemistry reaction.pCA-Fe-PA66 is self-cleaning, UV-blocking, photothermal conversion and antibacterial.The preparation method is mild, fast, simple, and expands the application of phenols.Prepared fabric has potential in...
这个反应按道理应该很容易进行,可是我一直做不出来,不知道原因,求指导: [box=white]1,双键、巯基、引发剂的比例是多少?我现在巯基与双键的比例约为1.5:1,引发剂安息香乙醚,AIBN,2959都试了,用量为1%wt。 2,关于三乙胺催化体系,不能用于水相吧? 3,体系必须是均相吗?异相反应可不可行?[/box] 求此方向大神...
反应体系要除氧;巯基原料有没有变质等。另外，你说的做不出来是指没有得到目标产物，还是说产率较低，...
Thiol-ene click chemistry. 来自 万方 喜欢 0 阅读量: 904 作者: Charles?E. Hoyle,Christopher?N. Bowman 摘要: Following Sharpless visionary characterization of several idealized reactions as click reactions, the materials science and synthetic chemistry communities have pursued numerous routes toward the ...