The existence of fluctuations of temperature has been a somewhat controversial topic in thermodynamics but nowadays it is recognized that they must be taken into account in small, finite systems. Although for nonequilibrium steady states superstatistics is becoming the extit{de facto} framework for ...
Hill T. L. ”Thermodynamics of Small Systems, Vol. 1 & 2, Benjamin, New York, 1963 & 1964.w24x T.L. Hill, Thermodynamics of Small Systems, Dover, New York, 1963.T. L. Hill, "Thermodynamics of Small Systems," Benja- min, New York, 1963....
stochasticthermodynamicsofsmallsystems TUZhan-Chun † (DepartmentofPhysics,BeijingNormalUniversity,Beijing100875,China) 摘要热力学是一个古老的课题,古典热力学以宏观的具有大粒子数的系统为研 究对象,自17世纪以来,科学家们构建了热力学的完备公理化体系。将热力学推广至小系 ...
The theoretical consideration is based on the analogy of interfacial thermodynamics and thermodynamics of small systems, leading to an expression of contribution of all components to micelle formation. The analysis of the equation gives the physicochemical meaning of coefficient of added salt effect, the...
《海外直订Small Systems and Fundamentals of Thermodynamics 小系统和热力学基础》,作者:海外直订Small Systems and Fundamentals of Thermodynamics 小系统和热力学基础Tovbin 著,出版社:CRC Press,ISBN:9781138587243。
Thermodynamics of Information Processing in Small Systems (Springer Theses, Springer, 2012). MATH Google Scholar Sagawa, T. & Ueda, M. Information Thermodynamics: Maxwell’s Demon in Nonequilibrium Dynamics 181–211 (Wiley-VCH, 2013). Google Scholar Parrondo, J. M. R. The Szilárd engine ...
Most natural systems operate far from equilibrium, displaying time-asymmetric, irreversible dynamics characterized by a positive entropy production while exchanging energy and matter with the environment. Although stochastic thermodynamics underpins the irreversible dynamics of small systems, the nonequilibrium ...
It is an exposition of the thermodynamics of a new non-statistical paradigm of physics and thermodynamics, which applies to both large and small systems (including one particle systems) in any state: thermodynamic (i.e. stable) equilibrium or not. It uses as its primitives the concepts of ...
By defining a binding energy we derive a consistent quantum formulation of the first law of thermodynamics, in which the role of correlations becomes evident, and this formulation reduces to the standard classical picture in relevant systems. We next discuss the emergence of the second law of ...
For large systems and low concentrations the approach is equivalent to the grand-canonical ensemble; for small systems we find significant deviations. We derive the detailed fluctuation theorem and Crooks’ work fluctuation theorem for structure-forming systems. The connection to the theory of particle...