Jones, Thermal decomposition of rhombohedral KClO3 from 29-76 kilobars and implications for the molar volume of fluid oxygen at high pressures, Am. Mineral. 86(11-12) (2001), pp. 1367-1379.Johnson, M. C., D. Walker, S. M. Clark, and R. L. Jones, Thermal decomposition of ...
Thermal decomposition of pyrotechnic mixtures containing sucrose with either potassium chlorate or potassium perchloratedoi:10.1016/j.combustflame.2005.01.002The thermal behavior of sucrose, KClO3, KClO4, and KClO3 + sucrose and KClO4 + sucrose mixtures was studied experimentally using differential...
Focused-microwave-induced combustion: Investigation of KClO3 thermal decomposition as O2 sourcePotassium chlorate is proposed here as a chemical source of O2 in focused-microwave-induced combustion. The thermal decomposition of this compound generates enough O2 to maintain the combustion and participate in...
This volume (10 cm3/mol) is in close agreement with volumes determined from studies of the thermal decomposition of KClO3 and KClO4 but is difficult to reconcile with fluid O2 volumes determined using shock wave techniques. If these new O2 partial molar volumes are relevant to molten iron ...
Potassium chlorate in presence of Cr(III), starts decomposing around 200掳C which is much below the decomposition temperature of pure KClO3. Each mole of Cr(III) takes up 8/3 moles of KClO3 to become oxidized into potassium dichromate.M.R. Udupa...
Only when a high-pressure rated sample holder was used the high temperature decomposition of the AN could be detected as an exothermic release. The testing was conducted during a proficiency (or round-robin type) test that included three U.S. Department of Energy and two U.S. Department of...
The results showed that pure lactose powder decomposes at about 358 in nitrogen atmosphere, while in similar 掳C condition decomposition temperature of pure KClO3, KMnO4, KNO3, KClO4, Ba(NO3)2, PbO2 and NH4ClO4 is 472, 290, 700, 592, 745, 436 and 321 , 掳C respectively. Based on ...
Based on the decomposition temperatures obtained and the resulted kinetic data (E, ΔG#, ΔH#, and ΔS#), obtained from differential scanning calorimetry (DSC), the thermal reactivity of the pyrotechnic mixtures found to decrease in the order Cu+NH4ClO4 >Cu+KClO3 >Cu+KClO4....
Thermogravimetric analysis (TGA) and differential thermal analysis (DTA) have been used to examine the thermal behavior of powdered zirconium with some pyrotechnic oxidants, in relation to the behavior of the individual constituents. The results showed that decomposition temperature for pure compounds (...