The reactivity of carbonium ions towards carbon monoxide is much higher than towards molecular hydrogen, which determines the rate of reaction for some tertiary and secondary alkyl cations and the rate of carbonylation of more stabilized carbonium ions. The chapter summarizes the quantitative aspects of...
Oxygen-containing carbons are promising supports and metal-free catalysts for many reactions. However, distinguishing the role of various oxygen functional groups and quantifying and tuning each functionality is still difficult. Here we investigate the r
Erratum: "Differential Scanning Calorimetry Study of the Reactivity of Carbon Anodes in Plastic Li-Ion Batteries" [J. Electrochem. Soc., 145, 472 (1998)] P Du,A. - 《Journal of the Electrochemical Society》 被引量: 0发表: 1998年 98/03833 Differential scanning calorimetry study of the ...
(95%, 84%). Consistent with the reactivity of carbon radical, the N-methylaniline with primary reaction site was also able to furnish the product (3aa) in a slightly compromised yield (67%). Remarkably, the substrate bearing a carboxylic acid group (3ab, 40%) was able to the protonate...
摘要: The reactivity of sodium inserted hard carbon with ethylene carbonate (EC), diethyl carbonate (DEC), dimethyl carbonate (DMC), EC:DEC, EC:DMC and NaPF关键词: Experimental/ association carbon electrolytes organic compounds sodium solvation solvent effects X-ray diffraction/ electrolytes sodium-...
ChemInform Abstract: STRUCTURAL EFFECTS ON THE REACTIVITY OF CARBON RADICALS IN HOMOLYTIC AROMATIC SUBSTITUTIONS. PART III. REACTION OF THE 1-ADAMANTYL RAD... Die homolytische Substitution von monosubstituierten Benzolen Ph-Xdurch das Adamantyl-( 1)-(Ad)-Radikal (aus Adamantan-( 1)-percarbonsLOR...
Reactivity of the carbon-carbon double bond towards nucleophilic additions. A DFT analysis The global and local electrophilicity indexes have been used to characterize the reactivity pattern of the C C double bond towards nucleophilic addition r... LR Domingo,P Pérez,RC Ramos - 《Tetrahedron》 被...
ChemInform Abstract: Reactions of Co-ordinated Ligands. Part 36. The Synthesis, Structure, and Reactivity of the Three-alkyne ′Fly-over′ Complex Mo2(μ-(... One-electron reduction of the Mo complex (I) with Mg amalgam (or Na amalgam) affords the three-alkyne ′fly-over′ complex (II...
amake your garden grow 做您的庭院增长[translate] ayes ... so far from you 是…. 到目前为止从您[translate] aThis might be a result of decreased reactivity of the b-carbon in these a,b-unsaturated 这在这些也许是b碳的减少的反应性的结果a, b不饱和[translate]...
Intrinsic CarbonCarbon Bond Reactivity at the Manganese Center of Oxalate Decarboxylase from Density Functional Theory 来自 Semantic Scholar 喜欢 0 阅读量: 36 作者:CH Chang,NGJ Richards 摘要: The detailed manganese-dependent chemistry employed by oxalate decarboxylase (OxDC) to catalyze the nonoxidative...