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Normally, thework-up of Swern oxidations is carried out by a routine fractioning between an aqueous and an organic phase. Somealdehydes with a high tendency to exist as a hydrate—typically, aldehydespossessing an alkoxy group at the a position—are hydrated during the standardwork-up, resulting...
Kinetics: The Rates of Reactions – Chemical kinetics – studies the reaction rates and mechanisms 16.1 Factors Affecting the Reaction Rate • Chemical nature of the reactants – each reaction has its own characteristic rate • Concentration – the reaction rate increases with increasing the react...
Feshbach resonances of a chemical reaction are transiently trapped quantum states along the reaction coordinate in the transition-state region. They not only have a profound influence on both the rate and product distribution, but also provide sensitive probes to the potential energy surface (PES) ...
Laser wavelength was set to 920 nm, and frames were captured at a rate of 683 ms per frame. Baseline activity was imaged while perfusing PBS. Sucrose (300 mM) and sucralose (15 mM) stimuli were perfused back to back and in reverse order to determine whether the same cell or ...
The sintering process was run in two steps; firstly, sintering temperature was set up at 600°C at a rate of 2 °C/min and held for 120 min so that the binder would be burned off. Then, the sintering temperature was increased up to 1200°C at a rate of 5 °C/min and held for...
The production processes, for their complexity, are generally affected by a significant scrap rate. Indeed, it is reported that the percentage of material inputs lost during the fabrication process is between 5% and 15% (Christian Hanisch et al., 2015; Schmuch et al., 2018). Given that ...
Totipotent cells hold enormous potential for regenerative medicine. Thus, the development of cellular models recapitulating totipotent-like features is of paramount importance. Cells resembling the totipotent cells of early embryos arise spontaneously in
The main protease of SARS-CoV-2 (Mpro) is an important target for developing COVID-19 therapeutics. Recent work has highlighted Mpro’s susceptibility to undergo redox-associated conformational changes in response to cellular and immune-system-induced ox
The particle size distribution curve was significantly shifted to the left, and the absolute value of zeta-potential increased. The new fermentation process soy sauce had a higher raw material utilization rate, smaller average particle size of 15.56 μm, and significantly higher stability when ...