A kinetic investigation of the mechanism of vinyl polymerizations initiated by mixtures of ammonium trichloroacetate and bis-acetylacetonato-copper(II)Kinetic results at 65掳 showed that the mechanism for the polymerization of methyl methacrylate, initiated by mixtures of ammonium trichloroacetate and ...
Journal of Polymer Science Part A Polymer ChemistryJenkins A D.The mechanism of initiation in vinyl polymerization. Journal of Polymer Science . 1958The mechanism of initiation in vinyl polymerization. Jenkins A D. Journal of Polymer Science . 1958...
vinyl polymerization [′vīn·əl pə‚lim·ə·rə′zā·shən] (organic chemistry) Addition polymerization where the unsaturated monomer contains a CH2=C‒group. McGraw-Hill Dictionary of Scientific & Technical Terms, 6E, Copyright © 2003 by The McGraw-Hill Companies, Inc. ...
The polymerization proceeded through a radical mechanism. Urea, known to be a denaturing agent for protein, was able to promote the polymerization. On addition of urea, it was found that the following three reactions took place: (1) promotion of the polymerization of MMA with lysozyme, Cu(II...
Using gas chromatography, the molar ratio of the amount of the above two acids was measured and classified into three types, according to the kind of amine used. From the results the reaction mechanism was discussed, and it was concluded that the oxygen which stands adjacent to the p-...
In the polymerization of MMA in the presence of CCl4, the initiating ability of PFM was much larger than that of ferrocene(Fc-H); the macromolecular effect of the initiator was very remarkable. The polymerization proceeded through a free-radical mechanism. The overall activation energy and ...
The self-assemblies of amphiphiles and the evolution of various aggregates inevitably affects the adsorption of surface-active materials on the oil-water interface, and therefore affect the thermodynamic and kinetic processes of lipid digestion. However, the details of the mechanism have not been ...
of rates of polymerization in γ and persulfate-initiated polymerizations together with electrospray mass spectrometry of aqueous phase oligomers, has shown that the mechanism for the induced decomposition of persulfate by vinyl acetate is chain transfer to initiator from aqueous-phase oligomeric radicals....
Kimura K, et al. Vimyl polymerization by metal Complex. XX VII. mechanistic study on the vinyl polymerization initiated by polyvi2 nylamine - Copper ( II) Chelate in dimethylsulfcxide Solution [J ] . J . macromol. Sci - chem , 1975 , A9 (8) : 1399 - 1412....
The initiation mechanism of the photopolymerization was postulated.doi:10.1080/10601327508056927Inaki, YoshiakiTakahashi, MasahikoTakemoto, KiichiTaylor & Francis GroupJournal of Macromolecular Science: Part A - Chemistry