Steiner T.The hydrogen bond in the solid state. Angewandte Chemie International Edition . 2002Steiner, T. The hydrogen bond in the solid state. Angew. Chem. Int. Ed. 2002, 41, 48-76.The hydrogen bond in the solid state. Steiner T. Angewandte Chemie International Edition . 2002...
Crystal structures of each species in the sequence shows that the hydrogen bonding matrix undergoes a series of changes in which there are preferred H-bond patterns which are maintained while others are broken and reformed in new patterns. The role of the H-bond matrix in controlling reaction ...
2a), we can infer the H-bond network structure of the guest water as shown in Fig. 3d. Due to the negligible H-bonds between guest water in site I and II (Fig. 2b), guest water molecules in site I have free or (considerably weak H-bonded) OH-arms. Fig. 3: Hydrogen bond ...
Emsley. De- termining hydrogen-bond strengths in the solid state by NMR: the quantitative measurement of homonuclear J couplings. Chem. Commun., 1852 (2002).Brown, S. P.; Peŕ ez-Torralba, M.; Sanz, D.; Claramunt, R. M.; Emsley, L. Determining Hydrogen-bond Strengths in the ...
Although a normal X–H···Y hydrogen bond is weak relative to covalent bonds, it is usually strong enough to hold two molecules together so that they have a definite structure in the ground state of the complex, although there are usually large-amplitude anharmonic zero-point fluctuations ab...
Give three examples of substances that would be expected to exhibit hydrogen bonding in the liquid state. Intermolecular Forces of Attraction: The particles in a sample of a chemical species can interact with each other because (1) they...
Which of the following substances exhibits strong hydrogen bonding in the liquid and solid states? (a) H2S (b) NH3 (c) SiH4 (d) HF (e) HCl Which of the following bonds can potentially contribute to the formation of a hy...
NMR 1H-Shielding Constants of Hydrogen-Bond Donor Reflect Manifestation of the Pauli Principle 2018, Journal of Physical Chemistry Letters Hydrogen atomic positions of O-H•••O hydrogen bonds in solution and in the solid state: The synergy of quantum chemical calculations with 1H-NMR chemic...
in opposite directions perpendicular to the H2S plane. Hence, the acceptor plane in the H2S dimer is nearly perpendicular to the SH bond of the donor involved in the hydrogen bond, in contrast with the H2O dimer where the OH bonds in the acceptor and the donor OH bond point to the ...
All-solid-state batteries (ASSBs) are promising alternatives to conventional lithium-ion batteries. ASSBs consist of solid-fast-ion-conducting electrolytes and electrodes that offer improved energy density, battery safety, specific power, and fast-charging capability. Despite decades of intensive research...