Reports on the bond dissociation free energies of the acidic H-A bonds in HA- radical anions. Estimation of the bond dissociation free energies using thermodynamic cycle; Factors determining mode of cleavage; Mechanism for the radical anion cleavage.Zhao...
bond dissociation energy (redirected fromBond dissociation energies) Medical [‚bänd di‚sō·sē¦ā·shən ′en·ər·jē] (physical chemistry) The change in enthalpy that occurs with the homolytic cleavage of a chemical bond under conditions of standard state. ...
Bond Dissociation Energies in DMSO Related to the Gas Phase. J Am Chem Soc 1991;113:9790-9795.Bordwell, F. G,Cheng, J.-P,Ji, G. et al.Bond dissociation energies in DMSO related to the gas phase. Journal of the American Chemical Society . 1991...
It is shown that the very large variations in the C H and C C homolytic bond-dissociation energies for a large variety of organic compounds can be rationalized in terms of the stabilization energies of these species and their corresponding radical(s). In most cases, these stabilization energies...
The homolytic bond dissociation energies (BDEs) for the N-H bonds in 21 anilines have been estimated by combination of the equilibrium acidities (pK(HA)) and the oxidation potentials of their conjugate anions, E(ox)(A-), in DMSO. The pK(HA) and E(ox)(A-) values for para-substituted...
Homolytic bond dissociation energies of the benzylic C-H bonds in radical anions and radical cations derived from fluorenes, triphenylmethanes, and related compoundsintermediates (and their reactions)structure (organic substances)ChemInform is a weeklying Service, delivering concise information at a ...
Bond dissociation energies of organic molecules Acc. Chem. Res., 36 (2003), p. 255 View in ScopusGoogle Scholar [5] H. Liu, P. Chen, X. Huang, X. Wei A physical organic strategy to predict and interpret stabilities of chemical bonds in energetic compounds for the discovery of thermal-...
The effect of bond functions on molecular dissociation energies Chemical Physics Letters(IF2.8)Pub Date : 11 May 1984, DOI:10.1016/0009-2614(84)85385-3 James S. Wright , Robert J. Buenker Multi-reference Cl calculations are reported for the ground states of HCl and N2at their equilibrium di...
B Ruscic,J Berkowitz - 《Journal of Chemical Physics》 被引量: 187发表: 1994年 First Transition Metal-Boryl Bond Energy and Quantitation of Large Differences in Sequential Bond Dissociation Energies of Boranes article{8171380, author = {RABLEN, PR and HARTWIG, JF and NOLAN, SP}, issn = {...
Thermochemical Study of the Cyanophenol Isomers estimation of the enthalpies of formation in the gaseous phase, the O—H bond dissociation energies, and the gas-phase acidities of the three cyanophenol... MAR Matos,MS Miranda,VMF Morais - 《Structural Chemistry》 被引量: 61发表: 2004年 Theoreti...