Tert-Butyl hydroperoxide or Tertiary Butyl Hydroperoxide or TBHPis organic peroxide widely used in a variety of oxidation processes. Tertiary Butyl hydro peroxide is an dangerous chemical that is highly reactive, flammable and toxic. Industrially, tert-butyl hydroperoxide is used as a radical polymeriza...
The formation of t-butylfurans has been reported by using a catalytic amount of iron(III) chloride in the presence of a large excess of iron(III) oxide and a source of the t-butyl cation. Furan has been converted directly, for example, into 2,5-di-t-butylfuran 〈82CI(L)603〉. ...
Representative of many specified amines are 1 - (b - dimethylamino - ethoxy) - 2 - and - 4 - (b - dimethylamino - ethylmercapto)-benzene, 1,2- and 1,4-bis-(g -dimethylaminopropylmercapto) - benzene and 1 - (b - butylmethylamino - ethoxy) - 4 - (b - butylmethylamino - ethyl...
Nevertheless, this reasoning allows an interpretation of the shift of δ + 5.5 reported for 1-n-butylphosphole; here there is a combination of the large β-deshielding and small γ-shielding, and if the former value is taken as +15.8 ppm from the t-butyl group calculation, then the γ...
5Mpotassiumhydroxide together with 3g of sodiumchloride was added. Two millilitres of tert-butyl-methyl ether was used for the extraction of the prepared sample. The organic layer was separated and then dried under mild nitrogen streamat roomtemperature to 100 L, and a 2- L aliquot was inject...
Tertiary amine esters e.g. ##STR1## their acid addition salts and their quaternary ammonium compounds.
In the Practice of our invention, we prefer to use as the inert liquid reaction solvent medium, 4 a neutral oxygen containing organic compound which is a solvent for the initial starting components. While solvents such as methyl alcohol, absolute ethyl alcohol, isopropyl alcohol, butyl alcohol, ...
butyl benzoic acid; (2) a mixture of m- and p-tertiary butyl toluene is oxidized as in (1) and treated with aqueous sodium hydroxide to a pH of 7.8, the aqueous phase acidified with sulphuric acid to pH 6.5 to give p-tertiary-butyl benzoic acid, further acidification of the mother-...