有机合成sharpless环氧化tbuoohvoacac2.pdf,Sharpless 环氧化 tBuOOH,VO(acac)2 HO HO O 区域选择性 OH OH Me Me VO(acac)2,TBHP,80 oC Me Me 区域选择 20:1 O Me Me HO HO VO(OEt)3 (0.2 eq.), Me Me MeO2C t-BuOOH (3.0 eq.)MeO2C CH2Cl2,25 oC,3 h, 氧 90%; Sharpless
Fernandez de la Pradilla, R
The VO(acac)2-tBuOOH system shows high oxidation reactivity for secondary alcohols to give ketones.doi:10.1016/S0040-4039(01)99834-XKiyotomi KanedaYasuyuki KawanishiKoichiro JitsukawaShiichiro TeranishiElsevier BVTetrahedron LettersKaneda, K., Kawanishi, Y., Jitsukawa, K., Teranishi, S. (1983) ...