【氟离子对Si-O键和Si-C键的断裂】 Compound1(33 mg, 0.042 mmol) wasdissolved in THF and TBAF (0.070 mL 1M in THF containing 18.4 mg, 0.070 mmol) was added, and the solution stirred at room temperaturefor48 h under a...
中文名称:四丁基氟化铵(TBAF) 中文别名:四丁基氟化铵四氢呋喃溶液;氧化铝负载四丁基氟化铵;TBAF 溶液;四丁基氟化铵四氢呋喃水溶液;氟化四丁铵;四正丁基氟化铵, 1M SOLN. IN THF;四正丁基氟化铵, 75% W/W AQ. SOLN.;四丁基氟化铵(含三个结晶水) 英文名称:Tetrabutylammonium fluoride CAS No:429-41-4 ...
To a solution of THP ether 1 (1.7 g, 3.3 mmol) in THF (10 mL) was added a 1 M solution of tetrabutylammoniumfluoride in THF (5 mL, 5 mmol) at 22-24oC. The solution was stirredfor 2 h and diluted with 100 mL (1:1) of Et2O/EtOAc solution. Theo...
unsaturated aldehydes in high regio- and diastereoselectivities under mild conditions is achieved. 4) A highly efficient stereoselective synthesis of (Z)-monofluoroenals from acyclic β-halo-enals in the presence of TBAF in THF under mild conditions is described. In practice, it is a tandem elimi...