Alkylchromium reactions: The reaction of functionalized alkylhalides under mild cobalt and chromium catalysis opens new perspectives for highly chemoselective C–C-couplings with complex substrates, for example, in total synthesis. ; The scope of chromium(II)/cobalt(I)-catalyzed Takai–Utimoto ...
A Variant of the TakaiUtimoto Reaction of Acrolein Acetals with Aldehydes Catalytic in Chromium: A Highly Stereoselective Route to Anti Diol Derivativesaddition reactionsstereochemistry (general, optical resolution)alcohols (acyclic compounds)alcohols (benzene compounds)...
Discusses the Takai-Utimoto reaction of acrolein acetals with aldehydes. Methods provided for the stereo-selective construction of arrays of acyclin stereogenic centers; Methodology of the reaction; Observations made from the reaction; Optimized conditions from the experiment.Boeckman...