Re: what do t2g and eg orbitals stand for « Reply #1 on: June 26, 2006, 09:32:26 AM » I read something about this in Atkins, Physical Chemistrythe letters say how many orbitals of the same symmetry are combinedOne orbital you call a or b (depending on something I don't kn...
We studied the influence of the trigonal distortion of the regular octahedron along the (111) direction, as found in the CoO2 layers. Under this distortion the t2g orbitals split into one a1g and two degenerate eg′ orbitals. We focused on the relative order of these orbitals. Using ...
This would arise from the orthogonality of the three t2g orbitals occupied by the unpaired electrons of Cr(III) and the two eg orbitals occupied by the unpaired electrons of Ni(II). The first compound with Cr(III)-Ni(II) interactions has been synthesized. This compound is {Cr[(ox)Ni(...
Finally, new data for the 螕8g (2 Eg ) and 螕6g (2 T 1g ) states at 1路2 渭m are given, completing the data set for the t 2g 3 transitions of IrF6.J.D. Webb & E.R. BernsteinDepartment of ChemistryMolecular Physics
Orbital ordering in crystals with degenerate localized levels Eg and T2g is investigated on the basis of the symmetry of atomic density matrices and their transformation properties. During ordering processes, several kinds of local state... Jirák - 《Physical Review B Condensed Matter》 被引量: ...
eg transfer and ammine vs. aqua ligands Electron-transfer matrix elements are calculated for several pairs of transition-metal complexes of the type ML/sub 6//sup 2 +/-ML/sub 6//sup 3 +/, chosen ... M Newton - 《Journal of Physical Chemistry》 被引量: 0发表: 1986年 Unusual ligand ...
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