Gupta, ShradheyParida, Keshaba NandaMukherjee, PuspalSen, PratikSpringer USJournal of Solution ChemistryGupta, S.; Parida, K.N.; Mukherjee, P.; Sen, P. Mixed solvent chemistry through synergistic solvation: Structure, property and function of t-butanol-dichloromethane binary solvent mixtures. J....
1. Identify the Reactants: - The two alcohols in question are t-butanol (tert-butanol) and n-butanol (normal butanol). - Tert-butanol has the structure (CH₃)₃COH, while n-butanol has the structure CH₃CH₂CH₂OH.
Other factors, some chemical and some related to the agitation, may be important, but the problem of predicting molecular structure remains unresolved.Access through your organization Check access to the full text by signing in through your organization. Access through your organization References (...
The pentasil structures are very thermal and acid stable. They are synthesized in the presence of ammonium ions, which become an integral part of the structure. Heating up to 600° C. decomposes the organic cations leaving the highly porous structure. ...
Shradhey GuptaKeshaba Nanda ParidaPuspal MukherjeePratik SenJournal of Solution ChemistryGupta, S.; Parida, K.N.; Mukherjee, P.; Sen, P. Mixed solvent chemistry through synergistic solvation: Structure, property and function of t-butanol-dichloromethane binary solvent mixtures. J. Solut. Chem. ...
The structural contribution to the shift in the TSVM of aqueous t-butanol by the addition of alkali halides was found to be in the order NaCl > KCl > RbCl and KCl > KBr > KI, thereby indicating that Na+ > K+ > Rb+ and Cl > Br > I in disrupting the hydrogen-bonded structure of...
Raman linewidth study of hydration structure of t-butanol in aqueous solutionBibliography, Experimental/ associationmolecular spectral line breadthorganic compoundsRaman spectra of organic molecules and substances/ t-butanolaqueous solutionisotropic Raman linewidth...
( x 2EE ) > 0.14, ultrasonic speed decreases and isentropic compressibility increases with concentration of t -butanol indicating that the ternary solution behaves as normal solution wherein any further addition of 2EE or t -butanol leads to destabilization of the hydrogen bonded structure of ...
When the concentration of DMSO in the cosolvent (xDMSO) > 0.2, ultrasonic velocity decreases and adiabatic compressibility increases with concentration of t-butanol indicating that any further addition of DMSO or t-butanol leads to destabilization of the hydrogen bonded structure of water and t-...
The present results are compared with results from previouskinetic studies, structure–activity relationships (SARs), andtheoretical calculations and the discrepancies are discussed. Resultsfrom this work were combined with available high temperature (1200–1800K) rate coefficient data and room temperature ...