Synthesis of metal carbonylsUnited States Patent C 2,967,087 SYNTHESIS OF METAL CARBONYLS Thomas H. Coh'ield, Birmingham, Mich., assignor to Ethyl Corporation, New York, N.Y., a corporation of Delaware i N Drawing. Filed 13, 1957, Ser. No. 645,674doi:US2967087 ACoffield, Thomas H...
XVI. METAL-METAL MULTIPLE BONDS: SYNTHESIS, CRYSTAL AND MOLECULAR STRUCTURE OF TRI-μ-CARBONYL-BIS((η5-PENTAMETHYLCYCLOPENTADIENYL)MANGANESE)(MN.TPLBOND# .MN) - THE FIRST MANGANESE-MANGANESE TRIPLE BONDChemInform Abstract: SYNTHESES OF METAL CARBONYLS. XVI. METAL-METAL MULTIPLE BONDS: SYNTHESIS, ...
Despite the century-long history, the chemistry of metal carbonyls is still developing. However, up to now there has been insufficient progress in the development of new effective synthetic methods for metal carbonyls and their derivatives. This paper reports the results of our studies in the ...
Considering metal complexes as matrix-isolated metal ions or atoms, electrochemical reduction of solvates or complexes has been used to promote the exchange of hard for soft ligands and so to prepare metal carbonyls and metal carbonyl derivatives. The electrochemical procedure offers the additional ...
ChemInform Abstract: CHEMISTRY OF THE METAL CARBONYLS. PART 78. SYNTHESIS AND X‐RAY CRYSTAL STRUCTURES OF (NIOS3(μ‐H)2(μ‐CO)2(CO)8(PPH3)2) AND (OS3RH(μ‐H)2(ACAC)(CO)10) (ACAC = ACETYLACETONATE)structure (organic substances...
Chemistry of the metal carbonyls. Part LXIX. Synthesis and reactions of complexes of manganese containing the substituted and unsubstituted 2,5-dioxacyclop... Chemistry of the metal carbonyls. Part LXIX. Synthesis and reactions of complexes of manganese containing the substituted and unsubstituted 2,...
Anovel synthetic procedure, namely the reaction of metal carbonyls with a protonated anion at neutral to acid pH in biphasic water - acetone solution is shown to be applicable to the synthesis of materials isostruc- - tural with the iron - manganese phosphate minerals hureaulite and alluaudite....
Carboxylation of hydroxyarens with metal alkyl carbonates (naphthols) carboxylation and developing a new and simple method for the synthesis of hydroxybenzoic and hydroxynaphthoic acids having broad practical ... KA Suerbaev,MK Aldabergenov,NZ Kudaibergenov - 《Green Processing & Synthesis》 被引量...
ChemInform Abstract: SYNTHESIS OF HYDRIDO‐ AND DEUTERIO‐CARBONYL CLUSTER COMPLEXES OF RUTHENIUM, IRON‐RUTHENIUM, AND OSMIUM FROM METAL CARBONYLS AND HYDROGEN AT ATMOSPHERIC PRESSUREorgano‐iron compoundsorgano‐ruthenium compoundsorgano‐osmium compounds...
The reactions of group 6 metal carbonyls with soluble polytellurides, Tex2- (x = 1-4), have been investigated using a 3-fold excess of the metal carbonyls. Several novel products have been isolated and characterized as their PPh4+ salts, including [M4(CO)18(μ3-Te)2]2-, (M = Cr...