A new synthetic methodology has been employed replacing usual cobalt(II) salts by [Co(NH3)5Cl]Cl2 as a precursor. The coordination geometry of cobalt(II), CoN2S2, was found to be distorted tetrahedral, whereas the cobalt(III) coordination sphere, CoN4S2, is slightly distorted octahedral. ...
The reactivity of a ruthenium(III) ammine complex, [Ru(NH3)5Cl]Cl2, towards α-N-heterocyclic mono- and di-carboxylic acids. The synthesis and characterisa... Ruthenium (III) complexes containing one, two or three 伪-N-heterocyclic mono- and di-carboxylic acid groups were prepared from the...
Cobalt nanoparticles have been prepared by the chemical reduction of [Co(NH3)6]Cl3, [Co(NH3)5Cl]Cl2, and [Co(NH3)5ONO]Cl2 in alcoholic solution. The reaction of these complexes with hydrazine as a reducing agent were carried out at 70掳C and pH = 10鈥 12. The metallic nanoparticles...
oxidationnickelwater splittingA mononuclear nonheme manganese(IV)-oxo complex, [MnIV(O)(BQCN)]2+, was generated in the photocatalytic reaction of a manganese(II) complex, [MnII(BQCN)]2+, with [RuII(bpy)3]Cl2 as a photosensitizer, [CoIII(NH3)5Cl]Cl2 as a low-cost sacrificial electron...
Synthesis, crystal structure and thermal properties of [Co(NH3)5Cl]MO4 (M = Mo, W)tungstenmolybdenumcobaltcomplex saltcrystal chemistrysingle crystal X-ray diffractionthermal propertiesCrystal structures of [Co(NH 3 ) 5 Cl]MoO 4 and [Co(NH 3 ) 5 Cl]WO 4 complex salts are determined by ...
Ru(NH3)6Cl3 and [Ru(NH3)5Cl]Cl2, comprising, if the case arises, in addition at least one stabiliser such as previously mentioned.LEGRAND, CHRISTOPHE, F- MONS-EN-BAROEULCASTANET, YVES, F- HEMMORTREUX, ANDRE, F- HEMPETIT, FRANCIS, F- VILLENEUVE D'ASCQ...
ChemInform Abstract: Synthesis of Pentaamminechlorocobalt(III) Tetrachloropalladate(II) [Co(NH3)5Cl][PdCl4]palladium, Pdcobalt, Cochlorine, Clnitrogen, Nstructure (solids and liquids)ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about ...
Russian Journal of Inorganic ChemistryShubin YV, Zadesenets AV, Venediktov AB. Double complex salts [M(NH3)5Cl][M′Br4] (M = Rh, Ir, Co, Cr, Ru; M′ = Pt, Pd): synthesis, X-ray diffraction characterization, and thermal properties. Russ J Inorg Chem. 2006;51:202–9. ...
At higher temperature and pressure gallium metal reacts with ammonium halides NH4x (X = F, Cl) to the ammoniates [Ga(NH3)5Cl]Cl2 or Ga(NH3)3F3 and GaN [66]. Obtaining [Ga(NH3)5Cl]Cl2 and Ga(NH3)3F3 during ammonothermal crystal growth of GaN next to GaN confirms the assumption ...