of (S)-(+) or (R)-()-2-(2-isoindolinyl)butan-1-ol 1 reduced the six α-aminophenones 4–9 into the corresponding optically active β-aminoalcohols 10–15 whose ee's were in the range 40–97% after chromatography and recrystallization. The asymmetric reduction of the ortho-...
Synthesis of 10-arylpyrimido(4,5-b)quinoline-2,4(3H,10H)diones (10-aryl-5-deazaflavins) and their use in oxidations of alcohols and amines Treatment of aryl-bis (6-anilino-3-methyluracil-5-yl) methanes, which were prepared by the condensation of 6-anilino-3-methyluracils with aryl...
A new, stereocontrolled synthesis of equatorial alcohols by the ambiphilic reduction of cyclohexanonesreduction, hydrogenationdoi:10.1016/s0040-4039(00)89268-0Keiji MaruokaMinoru SakuraiHisashi Yamamoto
Reductive arylation of aliphatic and aromatic aldehydes with cyanoarenes by electrolysis for the synthesis of alcohols. Org. Lett. 23, 3472–3476 (2021). Article CAS PubMed Google Scholar Zhang, S. et al. Electrochemical arylation of aldehydes, ketones, and alcohols: from cathodic reduction to...
Activating raw, zero-valent metals is an essential capability for chemical processes, which include synthesis and catalysis. In recent years there has been the discovery and growing intensity in the use of mechanical action, through the utility of ball m
ChemInform Abstract: A Novel One-Pot Synthesis of Secondary Alcohols from EstersChemInform Abstract: A Novel One-Pot Synthesis of Secondary Alcohols from Estersdoi:10.1016/j.tetlet.2011.02.005Alkylation or vinylation by using organometallic reagents after partial reduction of carboxylic esters with LDBBA...
Perfluorinated chiral alcohols are interesting building blocks for pharmaceuticals and agrochemicals. Different chiral ( R)- and ( S)-configured perfluorinated alcohols were produced by asymmetric reduction of the corresponding ketones. Commercially available alcohol dehydrogenases were used as catalyst in comb...
Production of Mixed Alcohols from Bio-syngas over Mo-based Catalyst A series of Mo-based catalysts prepared by sol-gel method using citric acid as complexant were successfully applied in the high efficient production of mix... S Qiu,W Huang,Y Xu,... - 《Chinese Journal of Chemical Physics...
Fig. 2: Proposed photoenzymatic cascades to transform unsaturated fatty acids into secondary alcohols. aCascade 1 comprises the (stereoselective) addition of water to C=C-double bonds catalysed by fatty acid hydratases (FAHs) followed by the decarboxylation mediated by the photoactivated decarboxylase ...
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