alcohol method of synthesis by reduction of the ether bond by hydrogenation reactionPROBLEM TO BE SOLVED: To provide a synthetic method for alcohols by the reduction of an ether bond by a hydrogenation reaction.川波 肇マヤ チャタジー石坂 孝之...
Synthesis of renewable plasticizer alcohols by formal anti-Markovnikov hydration of terminal branched chain alkenes via a borane-free oxidation/reduction s... An efficient method for the formal anti-Markovnikov hydration of 1,1-disubstituted alkenes has been developed. The utility of the process has ...
A high yield one-pot synthesis of -amino alcohols from nitroarenes and 1,2-epoxides was developed, which utilizes inexpensive iron dust as a reducing agent and NH 4 Cl as the only additive in a 50% (v/v) ethanol solution. This new efficient synthetic approach tolerates a wide range of...
Practical synthesis of enantiopure gamma-amino alcohols by rhodium-catalyzed asymmetric hydrogenation of beta-secondary-amino ketones. Liu, D., et al., " Practical Synthesis of Enantiopure Gamma-Amino Alcohols by Rhodium-Catalyzed Asymmetric Hydrogenation of Beta-Secondary-Amino Ketones "... D Liu,W...
Synthesis of enantiomerically enriched α-hydroxy amides and β-amino alcohols has been accomplished by enantioselective reduction of α-keto amides with hydrosilanes. A series of α-keto amides were reduced in the presence of chiral CuII/( S )-DTBM-SEGPHOS catalyst to give the corresponding optic...
The selective removal of one oxygen atom from sulfones, without over-reduction to sulfide, is a challenging task. Now, through organocatalysis and incorporation of a cyano group into the sulfone, an asymmetric deoxygenation strategy has been developed, providing an efficient method for the synthesis...
MoV–MoVI mixed valence polyoxometalates for facile synthesis of stabilized metal nanoparticles: electrocatalytic oxidation of alcohols. J. Phys. Chem. C 111, 8145–8148 (2007). Article CAS Google Scholar Roch-Marchal, C., Hidalgo, T., Banh, H., Fischer, R. A. & Horcajada, P. A ...
摘要: A synthesis of 3,7-disubstituted tricyclo[3.3.0.03,7]octane-1,5-diols, 2, by intramolecular pinacol reduction of cis-1,5-disubstituted bicyclo[3.3.0]octane-3,7-diones, 1, with low valent titanium species, is described.关键词: CHIRAL SECONDARY ALLYLIC ALCOHOLS MITSUNOBU REACTION ...
Sin... EM Clarke,EA Emerson - 25 Years of Model Checking-history, Achievements, Perspectives 被引量: 2823发表: 2008年 Non-fermentative pathways for synthesis of branched-chain higher alcohols as biofuels Global energy and environmental problems have stimulated increased efforts towards synthesizing ...
R. Ruthenium-catalyzed asymmetric transfer hydrogenation of allylic alcohols by an enantioselective isomerization/transfer hydrogenation mechanism. Angew. Chem. Int. Ed. 51, 2106–2110 (2012). Article CAS Google Scholar Lin, L., Romano, C. & Mazet, C. Palladium-catalyzed long-range deconjugative...